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Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) dihydrate

In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2H(2)O, the Ni(II) cation is located on an inversion centre and is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The Ni—N distances range from 2.0594 (1...

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Autores principales: Lyubartseva, Ganna, Parkin, Sean, Mallik, Uma Prasad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790345/
https://www.ncbi.nlm.nih.gov/pubmed/24098167
http://dx.doi.org/10.1107/S1600536813024252
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author Lyubartseva, Ganna
Parkin, Sean
Mallik, Uma Prasad
author_facet Lyubartseva, Ganna
Parkin, Sean
Mallik, Uma Prasad
author_sort Lyubartseva, Ganna
collection PubMed
description In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2H(2)O, the Ni(II) cation is located on an inversion centre and is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The Ni—N distances range from 2.0594 (12) to 2.0664 (12) Å, intra-ligand N—Ni—N angles range from 84.59 (5) to 86.06 (5)°, and adjacent inter-ligand N—Ni—N angles range between 93.94 (5) and 95.41 (5)°. In the crystal, inversion-related pyrazole rings are π–π stacked, with an inter­planar spacing of 3.4494 (18) Å, forming chains that propagate parallel to the a-axis direction. Inter­molecular O—H⋯O hydrogen bonds are present between water mol­ecules and tri­fluoro­methane­sulfonate anions.
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spelling pubmed-37903452013-10-04 Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) dihydrate Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2H(2)O, the Ni(II) cation is located on an inversion centre and is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The Ni—N distances range from 2.0594 (12) to 2.0664 (12) Å, intra-ligand N—Ni—N angles range from 84.59 (5) to 86.06 (5)°, and adjacent inter-ligand N—Ni—N angles range between 93.94 (5) and 95.41 (5)°. In the crystal, inversion-related pyrazole rings are π–π stacked, with an inter­planar spacing of 3.4494 (18) Å, forming chains that propagate parallel to the a-axis direction. Inter­molecular O—H⋯O hydrogen bonds are present between water mol­ecules and tri­fluoro­methane­sulfonate anions. International Union of Crystallography 2013-09-04 /pmc/articles/PMC3790345/ /pubmed/24098167 http://dx.doi.org/10.1107/S1600536813024252 Text en © Lyubartseva et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lyubartseva, Ganna
Parkin, Sean
Mallik, Uma Prasad
Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) dihydrate
title Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) dihydrate
title_full Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) dihydrate
title_fullStr Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) dihydrate
title_full_unstemmed Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) dihydrate
title_short Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) dihydrate
title_sort bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κn (2))ethane]­nickel(ii) bis­(tri­fluoro­methane­sulfonate) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790345/
https://www.ncbi.nlm.nih.gov/pubmed/24098167
http://dx.doi.org/10.1107/S1600536813024252
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