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Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN (2))ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate
In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2H(2)O, the Ni(II) cation is located on an inversion centre and is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The Ni—N distances range from 2.0594 (1...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790345/ https://www.ncbi.nlm.nih.gov/pubmed/24098167 http://dx.doi.org/10.1107/S1600536813024252 |
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author | Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad |
author_facet | Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad |
author_sort | Lyubartseva, Ganna |
collection | PubMed |
description | In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2H(2)O, the Ni(II) cation is located on an inversion centre and is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The Ni—N distances range from 2.0594 (12) to 2.0664 (12) Å, intra-ligand N—Ni—N angles range from 84.59 (5) to 86.06 (5)°, and adjacent inter-ligand N—Ni—N angles range between 93.94 (5) and 95.41 (5)°. In the crystal, inversion-related pyrazole rings are π–π stacked, with an interplanar spacing of 3.4494 (18) Å, forming chains that propagate parallel to the a-axis direction. Intermolecular O—H⋯O hydrogen bonds are present between water molecules and trifluoromethanesulfonate anions. |
format | Online Article Text |
id | pubmed-3790345 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903452013-10-04 Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN (2))ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2H(2)O, the Ni(II) cation is located on an inversion centre and is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The Ni—N distances range from 2.0594 (12) to 2.0664 (12) Å, intra-ligand N—Ni—N angles range from 84.59 (5) to 86.06 (5)°, and adjacent inter-ligand N—Ni—N angles range between 93.94 (5) and 95.41 (5)°. In the crystal, inversion-related pyrazole rings are π–π stacked, with an interplanar spacing of 3.4494 (18) Å, forming chains that propagate parallel to the a-axis direction. Intermolecular O—H⋯O hydrogen bonds are present between water molecules and trifluoromethanesulfonate anions. International Union of Crystallography 2013-09-04 /pmc/articles/PMC3790345/ /pubmed/24098167 http://dx.doi.org/10.1107/S1600536813024252 Text en © Lyubartseva et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN (2))ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
title | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN
(2))ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
title_full | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN
(2))ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
title_fullStr | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN
(2))ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
title_full_unstemmed | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN
(2))ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
title_short | Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN
(2))ethane]nickel(II) bis(trifluoromethanesulfonate) dihydrate |
title_sort | bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κn
(2))ethane]nickel(ii) bis(trifluoromethanesulfonate) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790345/ https://www.ncbi.nlm.nih.gov/pubmed/24098167 http://dx.doi.org/10.1107/S1600536813024252 |
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