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[μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene)
The title compound, [FeZr(2)(C(5)H(5))(4)Cl(2)(C(13)H(18)B(2))], is a heteronuclear complex that consists of a [3]ferrocenophane moiety substituted at each cyclopentadienyl (Cp) ring by a BH(3) group; the BH(3) group is bonded via two H atoms to the Zr atom of the zirconocene chloride moiety in a...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790346/ https://www.ncbi.nlm.nih.gov/pubmed/24098168 http://dx.doi.org/10.1107/S1600536813023933 |
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author | Reichert, Adelina Lerner, Hans-Wolfram Wagner, Matthias Bolte, Michael |
author_facet | Reichert, Adelina Lerner, Hans-Wolfram Wagner, Matthias Bolte, Michael |
author_sort | Reichert, Adelina |
collection | PubMed |
description | The title compound, [FeZr(2)(C(5)H(5))(4)Cl(2)(C(13)H(18)B(2))], is a heteronuclear complex that consists of a [3]ferrocenophane moiety substituted at each cyclopentadienyl (Cp) ring by a BH(3) group; the BH(3) group is bonded via two H atoms to the Zr atom of the zirconocene chloride moiety in a bidentate fashion. The two Cp rings of the [3]ferrocenophane moiety are aligned at a dihedral angle of 8.9 (4)° arising from the strain of the propane-1,3-diyl bridge linking the two Cp rings. [One methylene group is disordered over two positions with a site-occupation factor of 0.552 (18) for the major occupied site.] The dihedral angles between the Cp rings at the two Zr atoms are 50.0 (3) and 51.7 (3)°. The bonding Zr⋯H distances are in the range 1.89 (7)–2.14 (7) Å. As the two Cp rings of the ferrocene unit are connected by an ansa bridge, the two Zr atoms approach each other at 6.485 (1) Å. The crystal packing features C—H⋯Cl interactions. |
format | Online Article Text |
id | pubmed-3790346 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903462013-10-04 [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) Reichert, Adelina Lerner, Hans-Wolfram Wagner, Matthias Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [FeZr(2)(C(5)H(5))(4)Cl(2)(C(13)H(18)B(2))], is a heteronuclear complex that consists of a [3]ferrocenophane moiety substituted at each cyclopentadienyl (Cp) ring by a BH(3) group; the BH(3) group is bonded via two H atoms to the Zr atom of the zirconocene chloride moiety in a bidentate fashion. The two Cp rings of the [3]ferrocenophane moiety are aligned at a dihedral angle of 8.9 (4)° arising from the strain of the propane-1,3-diyl bridge linking the two Cp rings. [One methylene group is disordered over two positions with a site-occupation factor of 0.552 (18) for the major occupied site.] The dihedral angles between the Cp rings at the two Zr atoms are 50.0 (3) and 51.7 (3)°. The bonding Zr⋯H distances are in the range 1.89 (7)–2.14 (7) Å. As the two Cp rings of the ferrocene unit are connected by an ansa bridge, the two Zr atoms approach each other at 6.485 (1) Å. The crystal packing features C—H⋯Cl interactions. International Union of Crystallography 2013-09-07 /pmc/articles/PMC3790346/ /pubmed/24098168 http://dx.doi.org/10.1107/S1600536813023933 Text en © Reichert et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Reichert, Adelina Lerner, Hans-Wolfram Wagner, Matthias Bolte, Michael [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
title | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
title_full | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
title_fullStr | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
title_full_unstemmed | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
title_short | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
title_sort | [μ-3,3′-bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790346/ https://www.ncbi.nlm.nih.gov/pubmed/24098168 http://dx.doi.org/10.1107/S1600536813023933 |
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