Di­bromido­bis­(2-methyl-1H-benzimidazole-κN (3))cadmium

In the title compound, [CdBr(2)(C(8)H(8)N(2))(2)], the Cd(II) atom has a distorted tetra­hedral coordination formed by the two imino N atoms of two 2-methyl­benzimidazole ligands and two terminal bromide ligands. The Cd(II) atom is slightly out of the benzimidazole planes by 0.320 (3) and 0.210 (3) ...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Bao-Cheng, Jin, Yan-Ling, Liu, Fa-Qian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790347/
https://www.ncbi.nlm.nih.gov/pubmed/24098169
http://dx.doi.org/10.1107/S1600536813024549
Descripción
Sumario:In the title compound, [CdBr(2)(C(8)H(8)N(2))(2)], the Cd(II) atom has a distorted tetra­hedral coordination formed by the two imino N atoms of two 2-methyl­benzimidazole ligands and two terminal bromide ligands. The Cd(II) atom is slightly out of the benzimidazole planes by 0.320 (3) and 0.210 (3) Å. The dihedral angle between the benzimidazole planes is 71.6 (2)°. In the crystal, mol­ecules are linked by N—H⋯Br hydrogen bonds into puckered layers parallel to (001).

Ejemplares similares