Di­bromido­bis­(2-methyl-1H-benzimidazole-κN (3))cadmium

In the title compound, [CdBr(2)(C(8)H(8)N(2))(2)], the Cd(II) atom has a distorted tetra­hedral coordination formed by the two imino N atoms of two 2-methyl­benzimidazole ligands and two terminal bromide ligands. The Cd(II) atom is slightly out of the benzimidazole planes by 0.320 (3) and 0.210 (3) ...

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Detalles Bibliográficos
Autores principales: Liu, Bao-Cheng, Jin, Yan-Ling, Liu, Fa-Qian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790347/
https://www.ncbi.nlm.nih.gov/pubmed/24098169
http://dx.doi.org/10.1107/S1600536813024549
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author Liu, Bao-Cheng
Jin, Yan-Ling
Liu, Fa-Qian
author_facet Liu, Bao-Cheng
Jin, Yan-Ling
Liu, Fa-Qian
author_sort Liu, Bao-Cheng
collection PubMed
description In the title compound, [CdBr(2)(C(8)H(8)N(2))(2)], the Cd(II) atom has a distorted tetra­hedral coordination formed by the two imino N atoms of two 2-methyl­benzimidazole ligands and two terminal bromide ligands. The Cd(II) atom is slightly out of the benzimidazole planes by 0.320 (3) and 0.210 (3) Å. The dihedral angle between the benzimidazole planes is 71.6 (2)°. In the crystal, mol­ecules are linked by N—H⋯Br hydrogen bonds into puckered layers parallel to (001).
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spelling pubmed-37903472013-10-04 Di­bromido­bis­(2-methyl-1H-benzimidazole-κN (3))cadmium Liu, Bao-Cheng Jin, Yan-Ling Liu, Fa-Qian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdBr(2)(C(8)H(8)N(2))(2)], the Cd(II) atom has a distorted tetra­hedral coordination formed by the two imino N atoms of two 2-methyl­benzimidazole ligands and two terminal bromide ligands. The Cd(II) atom is slightly out of the benzimidazole planes by 0.320 (3) and 0.210 (3) Å. The dihedral angle between the benzimidazole planes is 71.6 (2)°. In the crystal, mol­ecules are linked by N—H⋯Br hydrogen bonds into puckered layers parallel to (001). International Union of Crystallography 2013-09-07 /pmc/articles/PMC3790347/ /pubmed/24098169 http://dx.doi.org/10.1107/S1600536813024549 Text en © Liu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Bao-Cheng
Jin, Yan-Ling
Liu, Fa-Qian
Di­bromido­bis­(2-methyl-1H-benzimidazole-κN (3))cadmium
title Di­bromido­bis­(2-methyl-1H-benzimidazole-κN (3))cadmium
title_full Di­bromido­bis­(2-methyl-1H-benzimidazole-κN (3))cadmium
title_fullStr Di­bromido­bis­(2-methyl-1H-benzimidazole-κN (3))cadmium
title_full_unstemmed Di­bromido­bis­(2-methyl-1H-benzimidazole-κN (3))cadmium
title_short Di­bromido­bis­(2-methyl-1H-benzimidazole-κN (3))cadmium
title_sort di­bromido­bis­(2-methyl-1h-benzimidazole-κn (3))cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790347/
https://www.ncbi.nlm.nih.gov/pubmed/24098169
http://dx.doi.org/10.1107/S1600536813024549
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