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Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate

In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2CH(3)OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni—N distances range fr...

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Detalles Bibliográficos
Autores principales: Lyubartseva, Ganna, Parkin, Sean, Mallik, Uma Prasad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790348/
https://www.ncbi.nlm.nih.gov/pubmed/24098170
http://dx.doi.org/10.1107/S1600536813024653
Descripción
Sumario:In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2CH(3)OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni—N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N—Ni—N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N—Ni—N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O—H⋯O hydrogen bonds between methanol solvent mol­ecules and tri­fluoro­methane­sulfonate anions are observed.