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Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl-κN (2))ethane]nickel(II) bis(trifluoromethanesulfonate) methanol disolvate
In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2CH(3)OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni—N distances range fr...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790348/ https://www.ncbi.nlm.nih.gov/pubmed/24098170 http://dx.doi.org/10.1107/S1600536813024653 |
Sumario: | In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2CH(3)OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-methoxy-2,2,2-tris(pyrazol-1-yl)ethane ligands in a distorted octahedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni—N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N—Ni—N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N—Ni—N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O—H⋯O hydrogen bonds between methanol solvent molecules and trifluoromethanesulfonate anions are observed. |
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