Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate

In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2CH(3)OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni—N distances range fr...

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Autores principales: Lyubartseva, Ganna, Parkin, Sean, Mallik, Uma Prasad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790348/
https://www.ncbi.nlm.nih.gov/pubmed/24098170
http://dx.doi.org/10.1107/S1600536813024653
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author Lyubartseva, Ganna
Parkin, Sean
Mallik, Uma Prasad
author_facet Lyubartseva, Ganna
Parkin, Sean
Mallik, Uma Prasad
author_sort Lyubartseva, Ganna
collection PubMed
description In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2CH(3)OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni—N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N—Ni—N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N—Ni—N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O—H⋯O hydrogen bonds between methanol solvent mol­ecules and tri­fluoro­methane­sulfonate anions are observed.
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spelling pubmed-37903482013-10-04 Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Ni(C(12)H(14)N(6)O)(2)](CF(3)SO(3))(2)·2CH(3)OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni—N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N—Ni—N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N—Ni—N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O—H⋯O hydrogen bonds between methanol solvent mol­ecules and tri­fluoro­methane­sulfonate anions are observed. International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790348/ /pubmed/24098170 http://dx.doi.org/10.1107/S1600536813024653 Text en © Lyubartseva et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lyubartseva, Ganna
Parkin, Sean
Mallik, Uma Prasad
Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate
title Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate
title_full Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate
title_fullStr Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate
title_full_unstemmed Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate
title_short Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κN (2))ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate
title_sort bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-κn (2))ethane]­nickel(ii) bis­(tri­fluoro­methane­sulfonate) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790348/
https://www.ncbi.nlm.nih.gov/pubmed/24098170
http://dx.doi.org/10.1107/S1600536813024653
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AT parkinsean bis1methoxy222trispyrazol1ylkn2ethanenickeliibistrifluoromethanesulfonatemethanoldisolvate
AT mallikumaprasad bis1methoxy222trispyrazol1ylkn2ethanenickeliibistrifluoromethanesulfonatemethanoldisolvate

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