Di­chlorido­diphenyl­bis­(thio­urea-κS)tin(IV)

The title compound, [Sn(C(6)H(5))(2)Cl(2)(CH(4)N(2)S)(2)], has been obtained from the reaction between Sn(C(6)H(5))(2)Cl(2) and SC(NH(2))(2). The asymmetric unit consists of one half of the mol­ecular unit, the remainder generated by a twofold rotation axis located along the Cl—Sn—Cl bonds. The Sn(I...

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Autores principales: Sow, Yaya, Diop, Libasse, Molloy, Kieran C., Kociok-Köhn, Gabriele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790350/
https://www.ncbi.nlm.nih.gov/pubmed/24098172
http://dx.doi.org/10.1107/S1600536813024343
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author Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Köhn, Gabriele
author_facet Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Köhn, Gabriele
author_sort Sow, Yaya
collection PubMed
description The title compound, [Sn(C(6)H(5))(2)Cl(2)(CH(4)N(2)S)(2)], has been obtained from the reaction between Sn(C(6)H(5))(2)Cl(2) and SC(NH(2))(2). The asymmetric unit consists of one half of the mol­ecular unit, the remainder generated by a twofold rotation axis located along the Cl—Sn—Cl bonds. The Sn(IV) atom is coordinated by two phenyl groups, two Cl atoms and two thio­urea ligands in an all trans octa­hedral C(2)Cl(2)S(2) environment. Individual mol­ecules are connected through N—H⋯Cl hydrogen bonds, leading to a three-dimensional network structure. Intra­molecular N—H⋯Cl hydrogen bonds are also present.
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spelling pubmed-37903502013-10-04 Di­chlorido­diphenyl­bis­(thio­urea-κS)tin(IV) Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Köhn, Gabriele Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(6)H(5))(2)Cl(2)(CH(4)N(2)S)(2)], has been obtained from the reaction between Sn(C(6)H(5))(2)Cl(2) and SC(NH(2))(2). The asymmetric unit consists of one half of the mol­ecular unit, the remainder generated by a twofold rotation axis located along the Cl—Sn—Cl bonds. The Sn(IV) atom is coordinated by two phenyl groups, two Cl atoms and two thio­urea ligands in an all trans octa­hedral C(2)Cl(2)S(2) environment. Individual mol­ecules are connected through N—H⋯Cl hydrogen bonds, leading to a three-dimensional network structure. Intra­molecular N—H⋯Cl hydrogen bonds are also present. International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790350/ /pubmed/24098172 http://dx.doi.org/10.1107/S1600536813024343 Text en © Sow et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Köhn, Gabriele
Di­chlorido­diphenyl­bis­(thio­urea-κS)tin(IV)
title Di­chlorido­diphenyl­bis­(thio­urea-κS)tin(IV)
title_full Di­chlorido­diphenyl­bis­(thio­urea-κS)tin(IV)
title_fullStr Di­chlorido­diphenyl­bis­(thio­urea-κS)tin(IV)
title_full_unstemmed Di­chlorido­diphenyl­bis­(thio­urea-κS)tin(IV)
title_short Di­chlorido­diphenyl­bis­(thio­urea-κS)tin(IV)
title_sort di­chlorido­diphenyl­bis­(thio­urea-κs)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790350/
https://www.ncbi.nlm.nih.gov/pubmed/24098172
http://dx.doi.org/10.1107/S1600536813024343
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AT molloykieranc dichloridodiphenylbisthioureakstiniv
AT kociokkohngabriele dichloridodiphenylbisthioureakstiniv

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