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Poly[tetramethylammonium [tri-μ(2)-formato-κ(6) O:O′-manganate(II)]]
In the title compound, {(C(4)H(12)N)[Mn(HCO(2))(3)]}(n), the Mn(II) atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination spher...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790351/ https://www.ncbi.nlm.nih.gov/pubmed/24098173 http://dx.doi.org/10.1107/S1600536813024045 |
| _version_ | 1782286576681746432 |
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| author | Han, Cai-Yun Liu, Min-Min Dang, Qin-Qin |
| author_facet | Han, Cai-Yun Liu, Min-Min Dang, Qin-Qin |
| author_sort | Han, Cai-Yun |
| collection | PubMed |
| description | In the title compound, {(C(4)H(12)N)[Mn(HCO(2))(3)]}(n), the Mn(II) atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetramethylammonium cations, which lie across mirror planes and occupy the cavities in the polymer structure, form weak C—H⋯O hydrogen bonds with the formate ligands. |
| format | Online Article Text |
| id | pubmed-3790351 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37903512013-10-04 Poly[tetramethylammonium [tri-μ(2)-formato-κ(6) O:O′-manganate(II)]] Han, Cai-Yun Liu, Min-Min Dang, Qin-Qin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(4)H(12)N)[Mn(HCO(2))(3)]}(n), the Mn(II) atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetramethylammonium cations, which lie across mirror planes and occupy the cavities in the polymer structure, form weak C—H⋯O hydrogen bonds with the formate ligands. International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790351/ /pubmed/24098173 http://dx.doi.org/10.1107/S1600536813024045 Text en © Han et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Han, Cai-Yun Liu, Min-Min Dang, Qin-Qin Poly[tetramethylammonium [tri-μ(2)-formato-κ(6) O:O′-manganate(II)]] |
| title | Poly[tetramethylammonium [tri-μ(2)-formato-κ(6)
O:O′-manganate(II)]] |
| title_full | Poly[tetramethylammonium [tri-μ(2)-formato-κ(6)
O:O′-manganate(II)]] |
| title_fullStr | Poly[tetramethylammonium [tri-μ(2)-formato-κ(6)
O:O′-manganate(II)]] |
| title_full_unstemmed | Poly[tetramethylammonium [tri-μ(2)-formato-κ(6)
O:O′-manganate(II)]] |
| title_short | Poly[tetramethylammonium [tri-μ(2)-formato-κ(6)
O:O′-manganate(II)]] |
| title_sort | poly[tetramethylammonium [tri-μ(2)-formato-κ(6)
o:o′-manganate(ii)]] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790351/ https://www.ncbi.nlm.nih.gov/pubmed/24098173 http://dx.doi.org/10.1107/S1600536813024045 |
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