μ-(2,6-Bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κN)copper(II)]

In the title compound, [Cu(2)(C(19)H(31)N(4)O)(OH)(NCS)(2)], the mol­ecular structure of the dinuclear complex reveals two penta­coordinated Cu(II) ions, which are bridged by the phenolate O atom of the ligand and by an exogenous hydroxide ion. The bridging atoms occupy equatorial positions in the c...

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Detalles Bibliográficos
Autores principales: Meera, M. G., Selvaraj, P. Kamatchi, Viswanathan, B., Ramkumar, V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790352/
https://www.ncbi.nlm.nih.gov/pubmed/24098174
http://dx.doi.org/10.1107/S1600536813024768
Descripción
Sumario:In the title compound, [Cu(2)(C(19)H(31)N(4)O)(OH)(NCS)(2)], the mol­ecular structure of the dinuclear complex reveals two penta­coordinated Cu(II) ions, which are bridged by the phenolate O atom of the ligand and by an exogenous hydroxide ion. The bridging atoms occupy equatorial positions in the coordination sphere of the metal atoms and complete the equatorial coordination planes with two ligand N atoms, the apical positions being occupied by thio­cyanate N atoms. The crystal structure also features π–π stacking inter­actions involving the benzene rings with a centroid–centroid distance of 3.764 (4)Å. The crystal studied was a non-merohedral twin, with a refined BASF value of 0.203 (2)