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μ-(2,6-Bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κN)copper(II)]

In the title compound, [Cu(2)(C(19)H(31)N(4)O)(OH)(NCS)(2)], the mol­ecular structure of the dinuclear complex reveals two penta­coordinated Cu(II) ions, which are bridged by the phenolate O atom of the ligand and by an exogenous hydroxide ion. The bridging atoms occupy equatorial positions in the c...

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Autores principales: Meera, M. G., Selvaraj, P. Kamatchi, Viswanathan, B., Ramkumar, V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790352/
https://www.ncbi.nlm.nih.gov/pubmed/24098174
http://dx.doi.org/10.1107/S1600536813024768
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author Meera, M. G.
Selvaraj, P. Kamatchi
Viswanathan, B.
Ramkumar, V.
author_facet Meera, M. G.
Selvaraj, P. Kamatchi
Viswanathan, B.
Ramkumar, V.
author_sort Meera, M. G.
collection PubMed
description In the title compound, [Cu(2)(C(19)H(31)N(4)O)(OH)(NCS)(2)], the mol­ecular structure of the dinuclear complex reveals two penta­coordinated Cu(II) ions, which are bridged by the phenolate O atom of the ligand and by an exogenous hydroxide ion. The bridging atoms occupy equatorial positions in the coordination sphere of the metal atoms and complete the equatorial coordination planes with two ligand N atoms, the apical positions being occupied by thio­cyanate N atoms. The crystal structure also features π–π stacking inter­actions involving the benzene rings with a centroid–centroid distance of 3.764 (4)Å. The crystal studied was a non-merohedral twin, with a refined BASF value of 0.203 (2)
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spelling pubmed-37903522013-10-04 μ-(2,6-Bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κN)copper(II)] Meera, M. G. Selvaraj, P. Kamatchi Viswanathan, B. Ramkumar, V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(19)H(31)N(4)O)(OH)(NCS)(2)], the mol­ecular structure of the dinuclear complex reveals two penta­coordinated Cu(II) ions, which are bridged by the phenolate O atom of the ligand and by an exogenous hydroxide ion. The bridging atoms occupy equatorial positions in the coordination sphere of the metal atoms and complete the equatorial coordination planes with two ligand N atoms, the apical positions being occupied by thio­cyanate N atoms. The crystal structure also features π–π stacking inter­actions involving the benzene rings with a centroid–centroid distance of 3.764 (4)Å. The crystal studied was a non-merohedral twin, with a refined BASF value of 0.203 (2) International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790352/ /pubmed/24098174 http://dx.doi.org/10.1107/S1600536813024768 Text en © Meera et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meera, M. G.
Selvaraj, P. Kamatchi
Viswanathan, B.
Ramkumar, V.
μ-(2,6-Bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κN)copper(II)]
title μ-(2,6-Bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κN)copper(II)]
title_full μ-(2,6-Bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κN)copper(II)]
title_fullStr μ-(2,6-Bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κN)copper(II)]
title_full_unstemmed μ-(2,6-Bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κN)copper(II)]
title_short μ-(2,6-Bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κN)copper(II)]
title_sort μ-(2,6-bis{[3-(di­methyl­amino)­prop­yl]imino­meth­yl}-4-methyl­phenolato)-μ-hydroxido-bis­[(thio­cyanato-κn)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790352/
https://www.ncbi.nlm.nih.gov/pubmed/24098174
http://dx.doi.org/10.1107/S1600536813024768
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