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μ-(2,6-Bis{[3-(dimethylamino)propyl]iminomethyl}-4-methylphenolato)-μ-hydroxido-bis[(thiocyanato-κN)copper(II)]
In the title compound, [Cu(2)(C(19)H(31)N(4)O)(OH)(NCS)(2)], the molecular structure of the dinuclear complex reveals two pentacoordinated Cu(II) ions, which are bridged by the phenolate O atom of the ligand and by an exogenous hydroxide ion. The bridging atoms occupy equatorial positions in the c...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790352/ https://www.ncbi.nlm.nih.gov/pubmed/24098174 http://dx.doi.org/10.1107/S1600536813024768 |
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author | Meera, M. G. Selvaraj, P. Kamatchi Viswanathan, B. Ramkumar, V. |
author_facet | Meera, M. G. Selvaraj, P. Kamatchi Viswanathan, B. Ramkumar, V. |
author_sort | Meera, M. G. |
collection | PubMed |
description | In the title compound, [Cu(2)(C(19)H(31)N(4)O)(OH)(NCS)(2)], the molecular structure of the dinuclear complex reveals two pentacoordinated Cu(II) ions, which are bridged by the phenolate O atom of the ligand and by an exogenous hydroxide ion. The bridging atoms occupy equatorial positions in the coordination sphere of the metal atoms and complete the equatorial coordination planes with two ligand N atoms, the apical positions being occupied by thiocyanate N atoms. The crystal structure also features π–π stacking interactions involving the benzene rings with a centroid–centroid distance of 3.764 (4)Å. The crystal studied was a non-merohedral twin, with a refined BASF value of 0.203 (2) |
format | Online Article Text |
id | pubmed-3790352 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903522013-10-04 μ-(2,6-Bis{[3-(dimethylamino)propyl]iminomethyl}-4-methylphenolato)-μ-hydroxido-bis[(thiocyanato-κN)copper(II)] Meera, M. G. Selvaraj, P. Kamatchi Viswanathan, B. Ramkumar, V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(19)H(31)N(4)O)(OH)(NCS)(2)], the molecular structure of the dinuclear complex reveals two pentacoordinated Cu(II) ions, which are bridged by the phenolate O atom of the ligand and by an exogenous hydroxide ion. The bridging atoms occupy equatorial positions in the coordination sphere of the metal atoms and complete the equatorial coordination planes with two ligand N atoms, the apical positions being occupied by thiocyanate N atoms. The crystal structure also features π–π stacking interactions involving the benzene rings with a centroid–centroid distance of 3.764 (4)Å. The crystal studied was a non-merohedral twin, with a refined BASF value of 0.203 (2) International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790352/ /pubmed/24098174 http://dx.doi.org/10.1107/S1600536813024768 Text en © Meera et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Meera, M. G. Selvaraj, P. Kamatchi Viswanathan, B. Ramkumar, V. μ-(2,6-Bis{[3-(dimethylamino)propyl]iminomethyl}-4-methylphenolato)-μ-hydroxido-bis[(thiocyanato-κN)copper(II)] |
title | μ-(2,6-Bis{[3-(dimethylamino)propyl]iminomethyl}-4-methylphenolato)-μ-hydroxido-bis[(thiocyanato-κN)copper(II)] |
title_full | μ-(2,6-Bis{[3-(dimethylamino)propyl]iminomethyl}-4-methylphenolato)-μ-hydroxido-bis[(thiocyanato-κN)copper(II)] |
title_fullStr | μ-(2,6-Bis{[3-(dimethylamino)propyl]iminomethyl}-4-methylphenolato)-μ-hydroxido-bis[(thiocyanato-κN)copper(II)] |
title_full_unstemmed | μ-(2,6-Bis{[3-(dimethylamino)propyl]iminomethyl}-4-methylphenolato)-μ-hydroxido-bis[(thiocyanato-κN)copper(II)] |
title_short | μ-(2,6-Bis{[3-(dimethylamino)propyl]iminomethyl}-4-methylphenolato)-μ-hydroxido-bis[(thiocyanato-κN)copper(II)] |
title_sort | μ-(2,6-bis{[3-(dimethylamino)propyl]iminomethyl}-4-methylphenolato)-μ-hydroxido-bis[(thiocyanato-κn)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790352/ https://www.ncbi.nlm.nih.gov/pubmed/24098174 http://dx.doi.org/10.1107/S1600536813024768 |
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