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m-Xylylenediaminium diaquabis[dihydrogen diphosphato(2−)]cobaltate(II) dihydrate
In the title complex, (C(8)H(14)N(2))[Co(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion lies on an inversion center and is coordinated by two bidentate diphosphate ligands and two water molecules in a slightly distorted octahedral coordination geometry. The m-xylylenediaminium cation is locate...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790354/ https://www.ncbi.nlm.nih.gov/pubmed/24098176 http://dx.doi.org/10.1107/S160053681302535X |
| Sumario: | In the title complex, (C(8)H(14)N(2))[Co(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion lies on an inversion center and is coordinated by two bidentate diphosphate ligands and two water molecules in a slightly distorted octahedral coordination geometry. The m-xylylenediaminium cation is located on a twofold rotation axis. In the crystal, a three-dimensional supramolecular assembly is constructed by O—H⋯O and N—H⋯O hydrogen bonds between the organic cations, complex anions and uncoordinated water molecules. |
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