m-Xylylenediaminium di­aqua­bis­[di­hydrogen diphosphato(2−)]cobaltate(II) dihydrate

In the title complex, (C(8)H(14)N(2))[Co(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion lies on an inversion center and is coordinated by two bidentate diphosphate ligands and two water mol­ecules in a slightly distorted octa­hedral coordination geometry. The m-xylylenediaminium cation is locate...

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Detalles Bibliográficos
Autores principales: Elboulali, Adel, Akriche, Samah, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790354/
https://www.ncbi.nlm.nih.gov/pubmed/24098176
http://dx.doi.org/10.1107/S160053681302535X
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author Elboulali, Adel
Akriche, Samah
Rzaigui, Mohamed
author_facet Elboulali, Adel
Akriche, Samah
Rzaigui, Mohamed
author_sort Elboulali, Adel
collection PubMed
description In the title complex, (C(8)H(14)N(2))[Co(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion lies on an inversion center and is coordinated by two bidentate diphosphate ligands and two water mol­ecules in a slightly distorted octa­hedral coordination geometry. The m-xylylenediaminium cation is located on a twofold rotation axis. In the crystal, a three-dimensional supra­molecular assembly is constructed by O—H⋯O and N—H⋯O hydrogen bonds between the organic cations, complex anions and uncoordin­ated water mol­ecules.
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spelling pubmed-37903542013-10-04 m-Xylylenediaminium di­aqua­bis­[di­hydrogen diphosphato(2−)]cobaltate(II) dihydrate Elboulali, Adel Akriche, Samah Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, (C(8)H(14)N(2))[Co(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion lies on an inversion center and is coordinated by two bidentate diphosphate ligands and two water mol­ecules in a slightly distorted octa­hedral coordination geometry. The m-xylylenediaminium cation is located on a twofold rotation axis. In the crystal, a three-dimensional supra­molecular assembly is constructed by O—H⋯O and N—H⋯O hydrogen bonds between the organic cations, complex anions and uncoordin­ated water mol­ecules. International Union of Crystallography 2013-09-18 /pmc/articles/PMC3790354/ /pubmed/24098176 http://dx.doi.org/10.1107/S160053681302535X Text en © Elboulali et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Elboulali, Adel
Akriche, Samah
Rzaigui, Mohamed
m-Xylylenediaminium di­aqua­bis­[di­hydrogen diphosphato(2−)]cobaltate(II) dihydrate
title m-Xylylenediaminium di­aqua­bis­[di­hydrogen diphosphato(2−)]cobaltate(II) dihydrate
title_full m-Xylylenediaminium di­aqua­bis­[di­hydrogen diphosphato(2−)]cobaltate(II) dihydrate
title_fullStr m-Xylylenediaminium di­aqua­bis­[di­hydrogen diphosphato(2−)]cobaltate(II) dihydrate
title_full_unstemmed m-Xylylenediaminium di­aqua­bis­[di­hydrogen diphosphato(2−)]cobaltate(II) dihydrate
title_short m-Xylylenediaminium di­aqua­bis­[di­hydrogen diphosphato(2−)]cobaltate(II) dihydrate
title_sort m-xylylenediaminium di­aqua­bis­[di­hydrogen diphosphato(2−)]cobaltate(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790354/
https://www.ncbi.nlm.nih.gov/pubmed/24098176
http://dx.doi.org/10.1107/S160053681302535X
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AT rzaiguimohamed mxylylenediaminiumdiaquabisdihydrogendiphosphato2cobaltateiidihydrate

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