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Bis(η(2)-ethylene)(η(5)-indenyl)iridium(I)
The asymmetric unit of the title compound, [Ir(C(9)H(7))(C(2)H(4))(2)], consists of two independent molecules. The bonding between iridium and the five-membered ring of the indenyl ligand shows the usual asymmetry associated with the typical ring slippage responsible for the enhanced activity of in...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790355/ https://www.ncbi.nlm.nih.gov/pubmed/24098177 http://dx.doi.org/10.1107/S1600536813025300 |
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author | Merola, Joseph S. |
author_facet | Merola, Joseph S. |
author_sort | Merola, Joseph S. |
collection | PubMed |
description | The asymmetric unit of the title compound, [Ir(C(9)H(7))(C(2)H(4))(2)], consists of two independent molecules. The bonding between iridium and the five-membered ring of the indenyl ligand shows the usual asymmetry associated with the typical ring slippage responsible for the enhanced activity of indenyl metal compounds when compared with the analogous cyclopentadienyl metal compound. There are three short Ir—C bonds of 2.210 (3), 2.190 (4) and 2.220 (3) Å and two long Ir—C bonds to the C atoms that are part of the fused six-membered ring of 2.349 (4) and 2.366 (3) Å for one of the independent molecules [2.208 (4), 2.222 (3), 2.197 (4) Å for the short distances and 2.371 (3) and 2.358 (3) Å for the long distances in the second molecule]. This results in both indenyl ligands being slightly kinked, with dihedral angles of 6.8 (4)° and 6.5 (4)°. |
format | Online Article Text |
id | pubmed-3790355 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903552013-10-04 Bis(η(2)-ethylene)(η(5)-indenyl)iridium(I) Merola, Joseph S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ir(C(9)H(7))(C(2)H(4))(2)], consists of two independent molecules. The bonding between iridium and the five-membered ring of the indenyl ligand shows the usual asymmetry associated with the typical ring slippage responsible for the enhanced activity of indenyl metal compounds when compared with the analogous cyclopentadienyl metal compound. There are three short Ir—C bonds of 2.210 (3), 2.190 (4) and 2.220 (3) Å and two long Ir—C bonds to the C atoms that are part of the fused six-membered ring of 2.349 (4) and 2.366 (3) Å for one of the independent molecules [2.208 (4), 2.222 (3), 2.197 (4) Å for the short distances and 2.371 (3) and 2.358 (3) Å for the long distances in the second molecule]. This results in both indenyl ligands being slightly kinked, with dihedral angles of 6.8 (4)° and 6.5 (4)°. International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790355/ /pubmed/24098177 http://dx.doi.org/10.1107/S1600536813025300 Text en © Joseph S. Merola 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Merola, Joseph S. Bis(η(2)-ethylene)(η(5)-indenyl)iridium(I) |
title | Bis(η(2)-ethylene)(η(5)-indenyl)iridium(I) |
title_full | Bis(η(2)-ethylene)(η(5)-indenyl)iridium(I) |
title_fullStr | Bis(η(2)-ethylene)(η(5)-indenyl)iridium(I) |
title_full_unstemmed | Bis(η(2)-ethylene)(η(5)-indenyl)iridium(I) |
title_short | Bis(η(2)-ethylene)(η(5)-indenyl)iridium(I) |
title_sort | bis(η(2)-ethylene)(η(5)-indenyl)iridium(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790355/ https://www.ncbi.nlm.nih.gov/pubmed/24098177 http://dx.doi.org/10.1107/S1600536813025300 |
work_keys_str_mv | AT merolajosephs bisē2ethyleneē5indenyliridiumi |