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Bis­(η(2)-ethyl­ene)(η(5)-inden­yl)iridium(I)

The asymmetric unit of the title compound, [Ir(C(9)H(7))(C(2)H(4))(2)], consists of two independent mol­ecules. The bonding between iridium and the five-membered ring of the indenyl ligand shows the usual asymmetry associated with the typical ring slippage responsible for the enhanced activity of in...

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Autor principal: Merola, Joseph S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790355/
https://www.ncbi.nlm.nih.gov/pubmed/24098177
http://dx.doi.org/10.1107/S1600536813025300
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author Merola, Joseph S.
author_facet Merola, Joseph S.
author_sort Merola, Joseph S.
collection PubMed
description The asymmetric unit of the title compound, [Ir(C(9)H(7))(C(2)H(4))(2)], consists of two independent mol­ecules. The bonding between iridium and the five-membered ring of the indenyl ligand shows the usual asymmetry associated with the typical ring slippage responsible for the enhanced activity of indenyl metal compounds when compared with the analogous cyclo­penta­dienyl metal compound. There are three short Ir—C bonds of 2.210 (3), 2.190 (4) and 2.220 (3) Å and two long Ir—C bonds to the C atoms that are part of the fused six-membered ring of 2.349 (4) and 2.366 (3) Å for one of the independent mol­ecules [2.208 (4), 2.222 (3), 2.197 (4) Å for the short distances and 2.371 (3) and 2.358 (3) Å for the long distances in the second mol­ecule]. This results in both indenyl ligands being slightly kinked, with dihedral angles of 6.8 (4)° and 6.5 (4)°.
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spelling pubmed-37903552013-10-04 Bis­(η(2)-ethyl­ene)(η(5)-inden­yl)iridium(I) Merola, Joseph S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ir(C(9)H(7))(C(2)H(4))(2)], consists of two independent mol­ecules. The bonding between iridium and the five-membered ring of the indenyl ligand shows the usual asymmetry associated with the typical ring slippage responsible for the enhanced activity of indenyl metal compounds when compared with the analogous cyclo­penta­dienyl metal compound. There are three short Ir—C bonds of 2.210 (3), 2.190 (4) and 2.220 (3) Å and two long Ir—C bonds to the C atoms that are part of the fused six-membered ring of 2.349 (4) and 2.366 (3) Å for one of the independent mol­ecules [2.208 (4), 2.222 (3), 2.197 (4) Å for the short distances and 2.371 (3) and 2.358 (3) Å for the long distances in the second mol­ecule]. This results in both indenyl ligands being slightly kinked, with dihedral angles of 6.8 (4)° and 6.5 (4)°. International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790355/ /pubmed/24098177 http://dx.doi.org/10.1107/S1600536813025300 Text en © Joseph S. Merola 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Merola, Joseph S.
Bis­(η(2)-ethyl­ene)(η(5)-inden­yl)iridium(I)
title Bis­(η(2)-ethyl­ene)(η(5)-inden­yl)iridium(I)
title_full Bis­(η(2)-ethyl­ene)(η(5)-inden­yl)iridium(I)
title_fullStr Bis­(η(2)-ethyl­ene)(η(5)-inden­yl)iridium(I)
title_full_unstemmed Bis­(η(2)-ethyl­ene)(η(5)-inden­yl)iridium(I)
title_short Bis­(η(2)-ethyl­ene)(η(5)-inden­yl)iridium(I)
title_sort bis­(η(2)-ethyl­ene)(η(5)-inden­yl)iridium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790355/
https://www.ncbi.nlm.nih.gov/pubmed/24098177
http://dx.doi.org/10.1107/S1600536813025300
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