Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)

In the title compound, [HgI(2)(C(22)H(20)N(4))(2)], the Hg(II) cation is situated on a twofold rotation axis and is coordinated by two iodide anions and two imidazolyl N atoms in a distorted tetra­hedral geometry. In the crystal, C—H⋯I inter­actions link the mol­ecules into chains extending in [010]...

Descripción completa

Detalles Bibliográficos
Autores principales: Xi, Wen-Gang, Wu, Zhi-Chao, Zhou, Hong-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790356/
https://www.ncbi.nlm.nih.gov/pubmed/24098178
http://dx.doi.org/10.1107/S1600536813025191
Descripción
Sumario:In the title compound, [HgI(2)(C(22)H(20)N(4))(2)], the Hg(II) cation is situated on a twofold rotation axis and is coordinated by two iodide anions and two imidazolyl N atoms in a distorted tetra­hedral geometry. In the crystal, C—H⋯I inter­actions link the mol­ecules into chains extending in [010], which are further linked into sheets parallel to (100) through C—H⋯N hydrogen bonding inter­actions.

Ejemplares similares