Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)

In the title compound, [HgI(2)(C(22)H(20)N(4))(2)], the Hg(II) cation is situated on a twofold rotation axis and is coordinated by two iodide anions and two imidazolyl N atoms in a distorted tetra­hedral geometry. In the crystal, C—H⋯I inter­actions link the mol­ecules into chains extending in [010]...

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Detalles Bibliográficos
Autores principales: Xi, Wen-Gang, Wu, Zhi-Chao, Zhou, Hong-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790356/
https://www.ncbi.nlm.nih.gov/pubmed/24098178
http://dx.doi.org/10.1107/S1600536813025191
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author Xi, Wen-Gang
Wu, Zhi-Chao
Zhou, Hong-Ping
author_facet Xi, Wen-Gang
Wu, Zhi-Chao
Zhou, Hong-Ping
author_sort Xi, Wen-Gang
collection PubMed
description In the title compound, [HgI(2)(C(22)H(20)N(4))(2)], the Hg(II) cation is situated on a twofold rotation axis and is coordinated by two iodide anions and two imidazolyl N atoms in a distorted tetra­hedral geometry. In the crystal, C—H⋯I inter­actions link the mol­ecules into chains extending in [010], which are further linked into sheets parallel to (100) through C—H⋯N hydrogen bonding inter­actions.
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spelling pubmed-37903562013-10-04 Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II) Xi, Wen-Gang Wu, Zhi-Chao Zhou, Hong-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [HgI(2)(C(22)H(20)N(4))(2)], the Hg(II) cation is situated on a twofold rotation axis and is coordinated by two iodide anions and two imidazolyl N atoms in a distorted tetra­hedral geometry. In the crystal, C—H⋯I inter­actions link the mol­ecules into chains extending in [010], which are further linked into sheets parallel to (100) through C—H⋯N hydrogen bonding inter­actions. International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790356/ /pubmed/24098178 http://dx.doi.org/10.1107/S1600536813025191 Text en © Xi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xi, Wen-Gang
Wu, Zhi-Chao
Zhou, Hong-Ping
Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_full Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_fullStr Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_full_unstemmed Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_short Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_sort bis((e)-2-{3-[4-(1h-imidazol-1-yl-κn (3))styr­yl]-5,5-di­methyl­cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790356/
https://www.ncbi.nlm.nih.gov/pubmed/24098178
http://dx.doi.org/10.1107/S1600536813025191
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