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Tris[4-(dimethylamino)pyridine][tris(pyrazol-1-yl)methane]ruthenium(II) bis(hexafluoridophosphate) diethyl ether monosolvate
In the title compound, [Ru(C(10)H(10)N(6))(C(7)H(10)N(2))(3)](PF(6))(2)·C(4)H(10)O, the Ru(II) cation is coordinated by one tris(1-pyrazolyl)methane (Tpm) and three dimethylaminopyridine (dmap) ligands in a slightly distorted octahedral geometry. The asymmetric unit consists of one complex cation...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790357/ https://www.ncbi.nlm.nih.gov/pubmed/24098179 http://dx.doi.org/10.1107/S1600536813025245 |
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author | Coe, Benjamin J. Raftery, James Rusanova, Daniela |
author_facet | Coe, Benjamin J. Raftery, James Rusanova, Daniela |
author_sort | Coe, Benjamin J. |
collection | PubMed |
description | In the title compound, [Ru(C(10)H(10)N(6))(C(7)H(10)N(2))(3)](PF(6))(2)·C(4)H(10)O, the Ru(II) cation is coordinated by one tris(1-pyrazolyl)methane (Tpm) and three dimethylaminopyridine (dmap) ligands in a slightly distorted octahedral geometry. The asymmetric unit consists of one complex cation, two hexafluoridophosphate anions and one diethyl ether solvent molecule in general positions. Although quite a large number of ruthenium complexes of the facially coordinating tridentate Tpm ligand have been structurally characterized, this is only the second one containing three pyridyl co-ligands. The average Ru—N(Tpm) distance is 2.059 (12) Å, while the average Ru—N(dmap) [dmap = 4-(dimethylamino)pyridine] distance is somewhat longer at 2.108 (13) Å. The orientation of the dmap ligands varies greatly, with dihedral angles between the pyridyl and opposite pyrazolyl rings of 14.3 (2), 23.2 (2) and 61.2 (2)°. |
format | Online Article Text |
id | pubmed-3790357 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903572013-10-04 Tris[4-(dimethylamino)pyridine][tris(pyrazol-1-yl)methane]ruthenium(II) bis(hexafluoridophosphate) diethyl ether monosolvate Coe, Benjamin J. Raftery, James Rusanova, Daniela Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(C(10)H(10)N(6))(C(7)H(10)N(2))(3)](PF(6))(2)·C(4)H(10)O, the Ru(II) cation is coordinated by one tris(1-pyrazolyl)methane (Tpm) and three dimethylaminopyridine (dmap) ligands in a slightly distorted octahedral geometry. The asymmetric unit consists of one complex cation, two hexafluoridophosphate anions and one diethyl ether solvent molecule in general positions. Although quite a large number of ruthenium complexes of the facially coordinating tridentate Tpm ligand have been structurally characterized, this is only the second one containing three pyridyl co-ligands. The average Ru—N(Tpm) distance is 2.059 (12) Å, while the average Ru—N(dmap) [dmap = 4-(dimethylamino)pyridine] distance is somewhat longer at 2.108 (13) Å. The orientation of the dmap ligands varies greatly, with dihedral angles between the pyridyl and opposite pyrazolyl rings of 14.3 (2), 23.2 (2) and 61.2 (2)°. International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790357/ /pubmed/24098179 http://dx.doi.org/10.1107/S1600536813025245 Text en © Coe et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Coe, Benjamin J. Raftery, James Rusanova, Daniela Tris[4-(dimethylamino)pyridine][tris(pyrazol-1-yl)methane]ruthenium(II) bis(hexafluoridophosphate) diethyl ether monosolvate |
title | Tris[4-(dimethylamino)pyridine][tris(pyrazol-1-yl)methane]ruthenium(II) bis(hexafluoridophosphate) diethyl ether monosolvate |
title_full | Tris[4-(dimethylamino)pyridine][tris(pyrazol-1-yl)methane]ruthenium(II) bis(hexafluoridophosphate) diethyl ether monosolvate |
title_fullStr | Tris[4-(dimethylamino)pyridine][tris(pyrazol-1-yl)methane]ruthenium(II) bis(hexafluoridophosphate) diethyl ether monosolvate |
title_full_unstemmed | Tris[4-(dimethylamino)pyridine][tris(pyrazol-1-yl)methane]ruthenium(II) bis(hexafluoridophosphate) diethyl ether monosolvate |
title_short | Tris[4-(dimethylamino)pyridine][tris(pyrazol-1-yl)methane]ruthenium(II) bis(hexafluoridophosphate) diethyl ether monosolvate |
title_sort | tris[4-(dimethylamino)pyridine][tris(pyrazol-1-yl)methane]ruthenium(ii) bis(hexafluoridophosphate) diethyl ether monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790357/ https://www.ncbi.nlm.nih.gov/pubmed/24098179 http://dx.doi.org/10.1107/S1600536813025245 |
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