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Tris­[4-(di­methyl­amino)­pyridine][tris(pyra­zol-1-yl)methane]­­ruthenium(II) bis­(hexa­fluorido­phosphate) diethyl ether monosolvate

In the title compound, [Ru(C(10)H(10)N(6))(C(7)H(10)N(2))(3)](PF(6))(2)·C(4)H(10)O, the Ru(II) cation is coordinated by one tris­(1-pyrazol­yl)methane (Tpm) and three dimethylaminopyridine (dmap) ligands in a slightly distorted octa­hedral geometry. The asymmetric unit consists of one complex cation...

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Autores principales: Coe, Benjamin J., Raftery, James, Rusanova, Daniela
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790357/
https://www.ncbi.nlm.nih.gov/pubmed/24098179
http://dx.doi.org/10.1107/S1600536813025245
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author Coe, Benjamin J.
Raftery, James
Rusanova, Daniela
author_facet Coe, Benjamin J.
Raftery, James
Rusanova, Daniela
author_sort Coe, Benjamin J.
collection PubMed
description In the title compound, [Ru(C(10)H(10)N(6))(C(7)H(10)N(2))(3)](PF(6))(2)·C(4)H(10)O, the Ru(II) cation is coordinated by one tris­(1-pyrazol­yl)methane (Tpm) and three dimethylaminopyridine (dmap) ligands in a slightly distorted octa­hedral geometry. The asymmetric unit consists of one complex cation, two hexa­fluorido­phosphate anions and one diethyl ether solvent mol­ecule in general positions. Although quite a large number of ruthenium complexes of the facially coordinating tridentate Tpm ligand have been structurally characterized, this is only the second one containing three pyridyl co-ligands. The average Ru—N(Tpm) distance is 2.059 (12) Å, while the average Ru—N(dmap) [dmap = 4-(di­methyl­amino)­pyridine] distance is somewhat longer at 2.108 (13) Å. The orientation of the dmap ligands varies greatly, with dihedral angles between the pyridyl and opposite pyrazolyl rings of 14.3 (2), 23.2 (2) and 61.2 (2)°.
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spelling pubmed-37903572013-10-04 Tris­[4-(di­methyl­amino)­pyridine][tris(pyra­zol-1-yl)methane]­­ruthenium(II) bis­(hexa­fluorido­phosphate) diethyl ether monosolvate Coe, Benjamin J. Raftery, James Rusanova, Daniela Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(C(10)H(10)N(6))(C(7)H(10)N(2))(3)](PF(6))(2)·C(4)H(10)O, the Ru(II) cation is coordinated by one tris­(1-pyrazol­yl)methane (Tpm) and three dimethylaminopyridine (dmap) ligands in a slightly distorted octa­hedral geometry. The asymmetric unit consists of one complex cation, two hexa­fluorido­phosphate anions and one diethyl ether solvent mol­ecule in general positions. Although quite a large number of ruthenium complexes of the facially coordinating tridentate Tpm ligand have been structurally characterized, this is only the second one containing three pyridyl co-ligands. The average Ru—N(Tpm) distance is 2.059 (12) Å, while the average Ru—N(dmap) [dmap = 4-(di­methyl­amino)­pyridine] distance is somewhat longer at 2.108 (13) Å. The orientation of the dmap ligands varies greatly, with dihedral angles between the pyridyl and opposite pyrazolyl rings of 14.3 (2), 23.2 (2) and 61.2 (2)°. International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790357/ /pubmed/24098179 http://dx.doi.org/10.1107/S1600536813025245 Text en © Coe et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Coe, Benjamin J.
Raftery, James
Rusanova, Daniela
Tris­[4-(di­methyl­amino)­pyridine][tris(pyra­zol-1-yl)methane]­­ruthenium(II) bis­(hexa­fluorido­phosphate) diethyl ether monosolvate
title Tris­[4-(di­methyl­amino)­pyridine][tris(pyra­zol-1-yl)methane]­­ruthenium(II) bis­(hexa­fluorido­phosphate) diethyl ether monosolvate
title_full Tris­[4-(di­methyl­amino)­pyridine][tris(pyra­zol-1-yl)methane]­­ruthenium(II) bis­(hexa­fluorido­phosphate) diethyl ether monosolvate
title_fullStr Tris­[4-(di­methyl­amino)­pyridine][tris(pyra­zol-1-yl)methane]­­ruthenium(II) bis­(hexa­fluorido­phosphate) diethyl ether monosolvate
title_full_unstemmed Tris­[4-(di­methyl­amino)­pyridine][tris(pyra­zol-1-yl)methane]­­ruthenium(II) bis­(hexa­fluorido­phosphate) diethyl ether monosolvate
title_short Tris­[4-(di­methyl­amino)­pyridine][tris(pyra­zol-1-yl)methane]­­ruthenium(II) bis­(hexa­fluorido­phosphate) diethyl ether monosolvate
title_sort tris­[4-(di­methyl­amino)­pyridine][tris(pyra­zol-1-yl)methane]­­ruthenium(ii) bis­(hexa­fluorido­phosphate) diethyl ether monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790357/
https://www.ncbi.nlm.nih.gov/pubmed/24098179
http://dx.doi.org/10.1107/S1600536813025245
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