Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyl­titanium(IV)]

The molecule of the title compound, [Ti(2)(CH(3))(2)(CH(3)O)(2)(C(11)H(15)O)(4)] or {[Ti(Me)(μ-OCH(3))(OC(6)H(3)CMe(3)-2-Me-6)](2)}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the...

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Detalles Bibliográficos
Autores principales: Nielson, Alastair J., Shen, Chaohong, Waters, Joyce M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790360/
https://www.ncbi.nlm.nih.gov/pubmed/24098182
http://dx.doi.org/10.1107/S1600536813025634
Descripción
Sumario:The molecule of the title compound, [Ti(2)(CH(3))(2)(CH(3)O)(2)(C(11)H(15)O)(4)] or {[Ti(Me)(μ-OCH(3))(OC(6)H(3)CMe(3)-2-Me-6)](2)}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the two Ti(IV) atoms [Ti—O bond lengths of 1.9794 (12) and 2.0603 (12) Å] with the two phenolato ligands occupying the remaining basal sites [Ti—O 1.8218 (11) and 1.8135 (11) Å]. The Ti—O—C phenolato bond angles are similar at 161.24 (10) and 160.66 (11)°. The methyl ligand attached to the metal atom has a Ti—C bond length of 2.0878 (17) Å.

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