Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyl­titanium(IV)]

The molecule of the title compound, [Ti(2)(CH(3))(2)(CH(3)O)(2)(C(11)H(15)O)(4)] or {[Ti(Me)(μ-OCH(3))(OC(6)H(3)CMe(3)-2-Me-6)](2)}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the...

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Autores principales: Nielson, Alastair J., Shen, Chaohong, Waters, Joyce M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790360/
https://www.ncbi.nlm.nih.gov/pubmed/24098182
http://dx.doi.org/10.1107/S1600536813025634
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author Nielson, Alastair J.
Shen, Chaohong
Waters, Joyce M.
author_facet Nielson, Alastair J.
Shen, Chaohong
Waters, Joyce M.
author_sort Nielson, Alastair J.
collection PubMed
description The molecule of the title compound, [Ti(2)(CH(3))(2)(CH(3)O)(2)(C(11)H(15)O)(4)] or {[Ti(Me)(μ-OCH(3))(OC(6)H(3)CMe(3)-2-Me-6)](2)}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the two Ti(IV) atoms [Ti—O bond lengths of 1.9794 (12) and 2.0603 (12) Å] with the two phenolato ligands occupying the remaining basal sites [Ti—O 1.8218 (11) and 1.8135 (11) Å]. The Ti—O—C phenolato bond angles are similar at 161.24 (10) and 160.66 (11)°. The methyl ligand attached to the metal atom has a Ti—C bond length of 2.0878 (17) Å.
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spelling pubmed-37903602013-10-04 Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyl­titanium(IV)] Nielson, Alastair J. Shen, Chaohong Waters, Joyce M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [Ti(2)(CH(3))(2)(CH(3)O)(2)(C(11)H(15)O)(4)] or {[Ti(Me)(μ-OCH(3))(OC(6)H(3)CMe(3)-2-Me-6)](2)}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the two Ti(IV) atoms [Ti—O bond lengths of 1.9794 (12) and 2.0603 (12) Å] with the two phenolato ligands occupying the remaining basal sites [Ti—O 1.8218 (11) and 1.8135 (11) Å]. The Ti—O—C phenolato bond angles are similar at 161.24 (10) and 160.66 (11)°. The methyl ligand attached to the metal atom has a Ti—C bond length of 2.0878 (17) Å. International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790360/ /pubmed/24098182 http://dx.doi.org/10.1107/S1600536813025634 Text en © Nielson et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nielson, Alastair J.
Shen, Chaohong
Waters, Joyce M.
Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyl­titanium(IV)]
title Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyl­titanium(IV)]
title_full Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyl­titanium(IV)]
title_fullStr Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyl­titanium(IV)]
title_full_unstemmed Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyl­titanium(IV)]
title_short Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyl­titanium(IV)]
title_sort di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κo)methyl­titanium(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790360/
https://www.ncbi.nlm.nih.gov/pubmed/24098182
http://dx.doi.org/10.1107/S1600536813025634
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AT watersjoycem dimmethanolatobis2tertbutyl6methylphenolatokomethyltitaniumiv

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