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Bis((E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)

In the title complex, [HgI(2)(C(21)H(19)N(5))(2)], the Hg(II) ion is located on a twofold rotation axis and is coordinated by two I atoms and two N atoms from two (E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl)styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile ligands in a distorted tetra­hedral geomet...

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Detalles Bibliográficos
Autores principales: Wang, Lian-Ke, Zhu, Wei-Ju, Zhou, Hong-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790361/
https://www.ncbi.nlm.nih.gov/pubmed/24098183
http://dx.doi.org/10.1107/S160053681302518X
Descripción
Sumario:In the title complex, [HgI(2)(C(21)H(19)N(5))(2)], the Hg(II) ion is located on a twofold rotation axis and is coordinated by two I atoms and two N atoms from two (E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl)styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile ligands in a distorted tetra­hedral geometry. In the crystal, the mol­ecules are linked by inter­molecular π–π inter­actions between the triazole and benzene rings [centroid–centroid distance = 3.794 (3) Å] into a band extending in [010]. These bands are further connected by C—H⋯N hydrogen bonds into a two-dimensional network parallel to (100).