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Bis((E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styryl]cyclohex-2-enylidene}malononitrile)diiodidomercury(II)
In the title complex, [HgI(2)(C(21)H(19)N(5))(2)], the Hg(II) ion is located on a twofold rotation axis and is coordinated by two I atoms and two N atoms from two (E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl)styryl]cyclohex-2-enylidene}malononitrile ligands in a distorted tetrahedral geomet...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790361/ https://www.ncbi.nlm.nih.gov/pubmed/24098183 http://dx.doi.org/10.1107/S160053681302518X |
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author | Wang, Lian-Ke Zhu, Wei-Ju Zhou, Hong-Ping |
author_facet | Wang, Lian-Ke Zhu, Wei-Ju Zhou, Hong-Ping |
author_sort | Wang, Lian-Ke |
collection | PubMed |
description | In the title complex, [HgI(2)(C(21)H(19)N(5))(2)], the Hg(II) ion is located on a twofold rotation axis and is coordinated by two I atoms and two N atoms from two (E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl)styryl]cyclohex-2-enylidene}malononitrile ligands in a distorted tetrahedral geometry. In the crystal, the molecules are linked by intermolecular π–π interactions between the triazole and benzene rings [centroid–centroid distance = 3.794 (3) Å] into a band extending in [010]. These bands are further connected by C—H⋯N hydrogen bonds into a two-dimensional network parallel to (100). |
format | Online Article Text |
id | pubmed-3790361 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903612013-10-04 Bis((E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styryl]cyclohex-2-enylidene}malononitrile)diiodidomercury(II) Wang, Lian-Ke Zhu, Wei-Ju Zhou, Hong-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [HgI(2)(C(21)H(19)N(5))(2)], the Hg(II) ion is located on a twofold rotation axis and is coordinated by two I atoms and two N atoms from two (E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl)styryl]cyclohex-2-enylidene}malononitrile ligands in a distorted tetrahedral geometry. In the crystal, the molecules are linked by intermolecular π–π interactions between the triazole and benzene rings [centroid–centroid distance = 3.794 (3) Å] into a band extending in [010]. These bands are further connected by C—H⋯N hydrogen bonds into a two-dimensional network parallel to (100). International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790361/ /pubmed/24098183 http://dx.doi.org/10.1107/S160053681302518X Text en © Wang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Lian-Ke Zhu, Wei-Ju Zhou, Hong-Ping Bis((E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styryl]cyclohex-2-enylidene}malononitrile)diiodidomercury(II) |
title | Bis((E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl-κN
(4))styryl]cyclohex-2-enylidene}malononitrile)diiodidomercury(II) |
title_full | Bis((E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl-κN
(4))styryl]cyclohex-2-enylidene}malononitrile)diiodidomercury(II) |
title_fullStr | Bis((E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl-κN
(4))styryl]cyclohex-2-enylidene}malononitrile)diiodidomercury(II) |
title_full_unstemmed | Bis((E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl-κN
(4))styryl]cyclohex-2-enylidene}malononitrile)diiodidomercury(II) |
title_short | Bis((E)-2-{5,5-dimethyl-3-[4-(1H-1,2,4-triazol-1-yl-κN
(4))styryl]cyclohex-2-enylidene}malononitrile)diiodidomercury(II) |
title_sort | bis((e)-2-{5,5-dimethyl-3-[4-(1h-1,2,4-triazol-1-yl-κn
(4))styryl]cyclohex-2-enylidene}malononitrile)diiodidomercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790361/ https://www.ncbi.nlm.nih.gov/pubmed/24098183 http://dx.doi.org/10.1107/S160053681302518X |
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