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Bis((E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)

In the title complex, [HgI(2)(C(21)H(19)N(5))(2)], the Hg(II) ion is located on a twofold rotation axis and is coordinated by two I atoms and two N atoms from two (E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl)styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile ligands in a distorted tetra­hedral geomet...

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Detalles Bibliográficos
Autores principales: Wang, Lian-Ke, Zhu, Wei-Ju, Zhou, Hong-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790361/
https://www.ncbi.nlm.nih.gov/pubmed/24098183
http://dx.doi.org/10.1107/S160053681302518X
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author Wang, Lian-Ke
Zhu, Wei-Ju
Zhou, Hong-Ping
author_facet Wang, Lian-Ke
Zhu, Wei-Ju
Zhou, Hong-Ping
author_sort Wang, Lian-Ke
collection PubMed
description In the title complex, [HgI(2)(C(21)H(19)N(5))(2)], the Hg(II) ion is located on a twofold rotation axis and is coordinated by two I atoms and two N atoms from two (E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl)styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile ligands in a distorted tetra­hedral geometry. In the crystal, the mol­ecules are linked by inter­molecular π–π inter­actions between the triazole and benzene rings [centroid–centroid distance = 3.794 (3) Å] into a band extending in [010]. These bands are further connected by C—H⋯N hydrogen bonds into a two-dimensional network parallel to (100).
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spelling pubmed-37903612013-10-04 Bis((E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II) Wang, Lian-Ke Zhu, Wei-Ju Zhou, Hong-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [HgI(2)(C(21)H(19)N(5))(2)], the Hg(II) ion is located on a twofold rotation axis and is coordinated by two I atoms and two N atoms from two (E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl)styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile ligands in a distorted tetra­hedral geometry. In the crystal, the mol­ecules are linked by inter­molecular π–π inter­actions between the triazole and benzene rings [centroid–centroid distance = 3.794 (3) Å] into a band extending in [010]. These bands are further connected by C—H⋯N hydrogen bonds into a two-dimensional network parallel to (100). International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790361/ /pubmed/24098183 http://dx.doi.org/10.1107/S160053681302518X Text en © Wang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Lian-Ke
Zhu, Wei-Ju
Zhou, Hong-Ping
Bis((E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title Bis((E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_full Bis((E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_fullStr Bis((E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_full_unstemmed Bis((E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_short Bis((E)-2-{5,5-di­methyl-3-[4-(1H-1,2,4-triazol-1-yl-κN (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(II)
title_sort bis((e)-2-{5,5-di­methyl-3-[4-(1h-1,2,4-triazol-1-yl-κn (4))styr­yl]cyclo­hex-2-enyl­idene}malono­nitrile)­diiodido­mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790361/
https://www.ncbi.nlm.nih.gov/pubmed/24098183
http://dx.doi.org/10.1107/S160053681302518X
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