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{5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate
In the title complex, [Ni(C(17)H(16)N(2)O(5))]·2H(2)O, the Ni(II) ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790363/ https://www.ncbi.nlm.nih.gov/pubmed/24098185 http://dx.doi.org/10.1107/S1600536813026007 |
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author | Datta, Amitabha Huang, Jui-Hsien Sheu, Shiann-Cherng |
author_facet | Datta, Amitabha Huang, Jui-Hsien Sheu, Shiann-Cherng |
author_sort | Datta, Amitabha |
collection | PubMed |
description | In the title complex, [Ni(C(17)H(16)N(2)O(5))]·2H(2)O, the Ni(II) ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the three C atoms of the connecting 1,3-diaminopropane-2-ol, all atoms except the metal are disordered over two sets of sites with an occupacy ratio of 0.566 (3):0.434 (3). The central C atom of the major component is significantly out of the mean plane of the remaing atoms while the conformation of this ring in the minor component is noticeably different. In the crystal, O—H⋯O hydrogen bonds involving the lattice water molecules and the hydroxy groups are observed. |
format | Online Article Text |
id | pubmed-3790363 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903632013-10-04 {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate Datta, Amitabha Huang, Jui-Hsien Sheu, Shiann-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(17)H(16)N(2)O(5))]·2H(2)O, the Ni(II) ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the three C atoms of the connecting 1,3-diaminopropane-2-ol, all atoms except the metal are disordered over two sets of sites with an occupacy ratio of 0.566 (3):0.434 (3). The central C atom of the major component is significantly out of the mean plane of the remaing atoms while the conformation of this ring in the minor component is noticeably different. In the crystal, O—H⋯O hydrogen bonds involving the lattice water molecules and the hydroxy groups are observed. International Union of Crystallography 2013-09-25 /pmc/articles/PMC3790363/ /pubmed/24098185 http://dx.doi.org/10.1107/S1600536813026007 Text en © Datta et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Datta, Amitabha Huang, Jui-Hsien Sheu, Shiann-Cherng {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate |
title | {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate |
title_full | {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate |
title_fullStr | {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate |
title_full_unstemmed | {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate |
title_short | {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate |
title_sort | {5,5′-dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790363/ https://www.ncbi.nlm.nih.gov/pubmed/24098185 http://dx.doi.org/10.1107/S1600536813026007 |
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