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{5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylyli­dene)]diphenolato}nickel(II) dihydrate

In the title complex, [Ni(C(17)H(16)N(2)O(5))]·2H(2)O, the Ni(II) ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the...

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Autores principales: Datta, Amitabha, Huang, Jui-Hsien, Sheu, Shiann-Cherng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790363/
https://www.ncbi.nlm.nih.gov/pubmed/24098185
http://dx.doi.org/10.1107/S1600536813026007
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author Datta, Amitabha
Huang, Jui-Hsien
Sheu, Shiann-Cherng
author_facet Datta, Amitabha
Huang, Jui-Hsien
Sheu, Shiann-Cherng
author_sort Datta, Amitabha
collection PubMed
description In the title complex, [Ni(C(17)H(16)N(2)O(5))]·2H(2)O, the Ni(II) ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the three C atoms of the connecting 1,3-di­amino­propane-2-ol, all atoms except the metal are disordered over two sets of sites with an occupacy ratio of 0.566 (3):0.434 (3). The central C atom of the major component is significantly out of the mean plane of the remaing atoms while the conformation of this ring in the minor component is noticeably different. In the crystal, O—H⋯O hydrogen bonds involving the lattice water mol­ecules and the hy­droxy groups are observed.
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spelling pubmed-37903632013-10-04 {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylyli­dene)]diphenolato}nickel(II) dihydrate Datta, Amitabha Huang, Jui-Hsien Sheu, Shiann-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(17)H(16)N(2)O(5))]·2H(2)O, the Ni(II) ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the three C atoms of the connecting 1,3-di­amino­propane-2-ol, all atoms except the metal are disordered over two sets of sites with an occupacy ratio of 0.566 (3):0.434 (3). The central C atom of the major component is significantly out of the mean plane of the remaing atoms while the conformation of this ring in the minor component is noticeably different. In the crystal, O—H⋯O hydrogen bonds involving the lattice water mol­ecules and the hy­droxy groups are observed. International Union of Crystallography 2013-09-25 /pmc/articles/PMC3790363/ /pubmed/24098185 http://dx.doi.org/10.1107/S1600536813026007 Text en © Datta et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Datta, Amitabha
Huang, Jui-Hsien
Sheu, Shiann-Cherng
{5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylyli­dene)]diphenolato}nickel(II) dihydrate
title {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylyli­dene)]diphenolato}nickel(II) dihydrate
title_full {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylyli­dene)]diphenolato}nickel(II) dihydrate
title_fullStr {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylyli­dene)]diphenolato}nickel(II) dihydrate
title_full_unstemmed {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylyli­dene)]diphenolato}nickel(II) dihydrate
title_short {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylyli­dene)]diphenolato}nickel(II) dihydrate
title_sort {5,5′-dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl)bis(nitrilomethanylyli­dene)]diphenolato}nickel(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790363/
https://www.ncbi.nlm.nih.gov/pubmed/24098185
http://dx.doi.org/10.1107/S1600536813026007
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