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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate

In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rot...

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Detalles Bibliográficos
Autor principal: Zhong, Kai-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790364/
https://www.ncbi.nlm.nih.gov/pubmed/24098186
http://dx.doi.org/10.1107/S160053681302610X
Descripción
Sumario:In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol mol­ecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N(2)C(2) groups is 83.26 (13)°. In the crystal, the complex mol­ecule and the propane-1,2-diol mol­ecule are connected through a pair of O—H⋯O hydrogen bonds.