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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate
In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rot...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790364/ https://www.ncbi.nlm.nih.gov/pubmed/24098186 http://dx.doi.org/10.1107/S160053681302610X |
Sumario: | In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol molecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N(2)C(2) groups is 83.26 (13)°. In the crystal, the complex molecule and the propane-1,2-diol molecule are connected through a pair of O—H⋯O hydrogen bonds. |
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