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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate
In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rot...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790364/ https://www.ncbi.nlm.nih.gov/pubmed/24098186 http://dx.doi.org/10.1107/S160053681302610X |
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author | Zhong, Kai-Long |
author_facet | Zhong, Kai-Long |
author_sort | Zhong, Kai-Long |
collection | PubMed |
description | In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol molecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N(2)C(2) groups is 83.26 (13)°. In the crystal, the complex molecule and the propane-1,2-diol molecule are connected through a pair of O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3790364 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903642013-10-04 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate Zhong, Kai-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol molecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N(2)C(2) groups is 83.26 (13)°. In the crystal, the complex molecule and the propane-1,2-diol molecule are connected through a pair of O—H⋯O hydrogen bonds. International Union of Crystallography 2013-09-28 /pmc/articles/PMC3790364/ /pubmed/24098186 http://dx.doi.org/10.1107/S160053681302610X Text en © Kai-Long Zhong 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhong, Kai-Long Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate |
title | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate |
title_full | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate |
title_fullStr | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate |
title_full_unstemmed | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate |
title_short | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate |
title_sort | bis(1,10-phenanthroline-κ(2)
n,n′)(sulfato-κo)zinc(ii) propane-1,2-diol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790364/ https://www.ncbi.nlm.nih.gov/pubmed/24098186 http://dx.doi.org/10.1107/S160053681302610X |
work_keys_str_mv | AT zhongkailong bis110phenanthrolinek2nnsulfatokozinciipropane12diolmonosolvate |