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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate

In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rot...

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Autor principal: Zhong, Kai-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790364/
https://www.ncbi.nlm.nih.gov/pubmed/24098186
http://dx.doi.org/10.1107/S160053681302610X
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author Zhong, Kai-Long
author_facet Zhong, Kai-Long
author_sort Zhong, Kai-Long
collection PubMed
description In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol mol­ecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N(2)C(2) groups is 83.26 (13)°. In the crystal, the complex mol­ecule and the propane-1,2-diol mol­ecule are connected through a pair of O—H⋯O hydrogen bonds.
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spelling pubmed-37903642013-10-04 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate Zhong, Kai-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol mol­ecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N(2)C(2) groups is 83.26 (13)°. In the crystal, the complex mol­ecule and the propane-1,2-diol mol­ecule are connected through a pair of O—H⋯O hydrogen bonds. International Union of Crystallography 2013-09-28 /pmc/articles/PMC3790364/ /pubmed/24098186 http://dx.doi.org/10.1107/S160053681302610X Text en © Kai-Long Zhong 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhong, Kai-Long
Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate
title Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κO)zinc(II) propane-1,2-diol monosolvate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)(sulfato-κo)zinc(ii) propane-1,2-diol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790364/
https://www.ncbi.nlm.nih.gov/pubmed/24098186
http://dx.doi.org/10.1107/S160053681302610X
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