Tetra­butyl­ammonium butyl­tetra­chlorido­stannate(IV)

In the title compound, [N(C(4)H(9))(4)][Sn(C(4)H(9))Cl(4)], the Sn(IV) atom of the stannate anion has a trigonal-bipyramidal coordination sphere by two Cl atoms and one butyl chain in the equatorial plane and by two Cl atoms in the apical positions. Two of the four butyl chains of the tetra­butyl­am...

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Detalles Bibliográficos
Autores principales: Diop, Tidiane, van der Lee, Arie, Diop, Libasse
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790365/
https://www.ncbi.nlm.nih.gov/pubmed/24098187
http://dx.doi.org/10.1107/S1600536813026172
Descripción
Sumario:In the title compound, [N(C(4)H(9))(4)][Sn(C(4)H(9))Cl(4)], the Sn(IV) atom of the stannate anion has a trigonal-bipyramidal coordination sphere by two Cl atoms and one butyl chain in the equatorial plane and by two Cl atoms in the apical positions. Two of the four butyl chains of the tetra­butyl­ammonium cation are partially disordered, each with refined site occupancies of 0.691 (6):0.309 (6). Weak C—H⋯Cl hydrogen-bonding inter­actions help to consolidate the crystal packing, as well as a short Cl⋯Cl inter­action of 3.295 (2) Å.

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