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Pyridinium trans-diaquabis[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) urea monosolvate
The asymmetric unit of the title solvated molecular salt, (C(5)H(6)N)[Cr(C(2)O(4))(2)(H(2)O)(2)]·CO(NH(2))(2), contains half a formula unit. Each component is completed by crystallographic twofold symmetry: in the cation, one C and the N atom lie on the rotation axis; in the anion, the Cr(III) ion...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790368/ https://www.ncbi.nlm.nih.gov/pubmed/24098190 http://dx.doi.org/10.1107/S1600536813026135 |
Sumario: | The asymmetric unit of the title solvated molecular salt, (C(5)H(6)N)[Cr(C(2)O(4))(2)(H(2)O)(2)]·CO(NH(2))(2), contains half a formula unit. Each component is completed by crystallographic twofold symmetry: in the cation, one C and the N atom lie on the rotation axis; in the anion, the Cr(III) ion lies on the axis; in the solvent molecule, the C and the O atom lie on the axis. The aqua ligands are in a trans disposition in the resulting CrO(6) octahedron. In the crystal, the components are linked by O—H⋯O, N—H⋯O and N—H⋯(O,O) hydrogen bonds, generating a three-dimensional network. |
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