Pyridinium trans-di­aqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) urea monosolvate

The asymmetric unit of the title solvated mol­ecular salt, (C(5)H(6)N)[Cr(C(2)O(4))(2)(H(2)O)(2)]·CO(NH(2))(2), contains half a formula unit. Each component is completed by crystallographic twofold symmetry: in the cation, one C and the N atom lie on the rotation axis; in the anion, the Cr(III) ion...

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Autores principales: Bebga, Gouet, Signé, Martin, Nenwa, Justin, Mbarki, Mohammed, Fokwa, Boniface P. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790368/
https://www.ncbi.nlm.nih.gov/pubmed/24098190
http://dx.doi.org/10.1107/S1600536813026135
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author Bebga, Gouet
Signé, Martin
Nenwa, Justin
Mbarki, Mohammed
Fokwa, Boniface P. T.
author_facet Bebga, Gouet
Signé, Martin
Nenwa, Justin
Mbarki, Mohammed
Fokwa, Boniface P. T.
author_sort Bebga, Gouet
collection PubMed
description The asymmetric unit of the title solvated mol­ecular salt, (C(5)H(6)N)[Cr(C(2)O(4))(2)(H(2)O)(2)]·CO(NH(2))(2), contains half a formula unit. Each component is completed by crystallographic twofold symmetry: in the cation, one C and the N atom lie on the rotation axis; in the anion, the Cr(III) ion lies on the axis; in the solvent mol­ecule, the C and the O atom lie on the axis. The aqua ligands are in a trans disposition in the resulting CrO(6) octa­hedron. In the crystal, the components are linked by O—H⋯O, N—H⋯O and N—H⋯(O,O) hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-37903682013-10-04 Pyridinium trans-di­aqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) urea monosolvate Bebga, Gouet Signé, Martin Nenwa, Justin Mbarki, Mohammed Fokwa, Boniface P. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title solvated mol­ecular salt, (C(5)H(6)N)[Cr(C(2)O(4))(2)(H(2)O)(2)]·CO(NH(2))(2), contains half a formula unit. Each component is completed by crystallographic twofold symmetry: in the cation, one C and the N atom lie on the rotation axis; in the anion, the Cr(III) ion lies on the axis; in the solvent mol­ecule, the C and the O atom lie on the axis. The aqua ligands are in a trans disposition in the resulting CrO(6) octa­hedron. In the crystal, the components are linked by O—H⋯O, N—H⋯O and N—H⋯(O,O) hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2013-09-28 /pmc/articles/PMC3790368/ /pubmed/24098190 http://dx.doi.org/10.1107/S1600536813026135 Text en © Bebga et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bebga, Gouet
Signé, Martin
Nenwa, Justin
Mbarki, Mohammed
Fokwa, Boniface P. T.
Pyridinium trans-di­aqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) urea monosolvate
title Pyridinium trans-di­aqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) urea monosolvate
title_full Pyridinium trans-di­aqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) urea monosolvate
title_fullStr Pyridinium trans-di­aqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) urea monosolvate
title_full_unstemmed Pyridinium trans-di­aqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) urea monosolvate
title_short Pyridinium trans-di­aqua­bis­[oxalato(2−)-κ(2) O (1),O (2)]chromate(III) urea monosolvate
title_sort pyridinium trans-di­aqua­bis­[oxalato(2−)-κ(2) o (1),o (2)]chromate(iii) urea monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790368/
https://www.ncbi.nlm.nih.gov/pubmed/24098190
http://dx.doi.org/10.1107/S1600536813026135
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