6-Meth­oxy-4-(2,4,5-tri­meth­oxy­phen­yl)-2,2′-bi­pyridine-5-carbo­nitrile

In the title 3-cyano­pyridine derivative, C(21)H(19)N(3)O(4), the 3-cyano-substituted pyridine ring forms dihedral angles of 2.35 (5) and 41.60 (5)° with the unsubstituted pyridine and 2,4,5-trimeth­oxy-substituted benzene rings, respectively. The dihedral angle between the unsubstituted pyridine an...

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Autores principales: Chantrapromma, Suchada, Suwunwong, Thitipone, Ruanwas, Pumsak, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790375/
https://www.ncbi.nlm.nih.gov/pubmed/24098197
http://dx.doi.org/10.1107/S1600536813023891
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author Chantrapromma, Suchada
Suwunwong, Thitipone
Ruanwas, Pumsak
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Chantrapromma, Suchada
Suwunwong, Thitipone
Ruanwas, Pumsak
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Chantrapromma, Suchada
collection PubMed
description In the title 3-cyano­pyridine derivative, C(21)H(19)N(3)O(4), the 3-cyano-substituted pyridine ring forms dihedral angles of 2.35 (5) and 41.60 (5)° with the unsubstituted pyridine and 2,4,5-trimeth­oxy-substituted benzene rings, respectively. The dihedral angle between the unsubstituted pyridine and benzene rings is 39.84 (5)°. The meth­oxy groups form C(meth­yl)—O—C—(C,N) torsion angles in the range 0.80 (15)–11.45 (15)°. In the crystal, mol­ecules related by 2(1) screw axes are linked by weak C—H⋯N hydrogen bonds along [010]. In addition, weak C—H⋯π inter­actions and π–π stacking inter­actions between pyridine rings, with a centroid–centroid distance of 3.6448 (6) Å, are observed.
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spelling pubmed-37903752013-10-04 6-Meth­oxy-4-(2,4,5-tri­meth­oxy­phen­yl)-2,2′-bi­pyridine-5-carbo­nitrile Chantrapromma, Suchada Suwunwong, Thitipone Ruanwas, Pumsak Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title 3-cyano­pyridine derivative, C(21)H(19)N(3)O(4), the 3-cyano-substituted pyridine ring forms dihedral angles of 2.35 (5) and 41.60 (5)° with the unsubstituted pyridine and 2,4,5-trimeth­oxy-substituted benzene rings, respectively. The dihedral angle between the unsubstituted pyridine and benzene rings is 39.84 (5)°. The meth­oxy groups form C(meth­yl)—O—C—(C,N) torsion angles in the range 0.80 (15)–11.45 (15)°. In the crystal, mol­ecules related by 2(1) screw axes are linked by weak C—H⋯N hydrogen bonds along [010]. In addition, weak C—H⋯π inter­actions and π–π stacking inter­actions between pyridine rings, with a centroid–centroid distance of 3.6448 (6) Å, are observed. International Union of Crystallography 2013-09-04 /pmc/articles/PMC3790375/ /pubmed/24098197 http://dx.doi.org/10.1107/S1600536813023891 Text en © Chantrapromma et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chantrapromma, Suchada
Suwunwong, Thitipone
Ruanwas, Pumsak
Quah, Ching Kheng
Fun, Hoong-Kun
6-Meth­oxy-4-(2,4,5-tri­meth­oxy­phen­yl)-2,2′-bi­pyridine-5-carbo­nitrile
title 6-Meth­oxy-4-(2,4,5-tri­meth­oxy­phen­yl)-2,2′-bi­pyridine-5-carbo­nitrile
title_full 6-Meth­oxy-4-(2,4,5-tri­meth­oxy­phen­yl)-2,2′-bi­pyridine-5-carbo­nitrile
title_fullStr 6-Meth­oxy-4-(2,4,5-tri­meth­oxy­phen­yl)-2,2′-bi­pyridine-5-carbo­nitrile
title_full_unstemmed 6-Meth­oxy-4-(2,4,5-tri­meth­oxy­phen­yl)-2,2′-bi­pyridine-5-carbo­nitrile
title_short 6-Meth­oxy-4-(2,4,5-tri­meth­oxy­phen­yl)-2,2′-bi­pyridine-5-carbo­nitrile
title_sort 6-meth­oxy-4-(2,4,5-tri­meth­oxy­phen­yl)-2,2′-bi­pyridine-5-carbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790375/
https://www.ncbi.nlm.nih.gov/pubmed/24098197
http://dx.doi.org/10.1107/S1600536813023891
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AT suwunwongthitipone 6methoxy4245trimethoxyphenyl22bipyridine5carbonitrile
AT ruanwaspumsak 6methoxy4245trimethoxyphenyl22bipyridine5carbonitrile
AT quahchingkheng 6methoxy4245trimethoxyphenyl22bipyridine5carbonitrile
AT funhoongkun 6methoxy4245trimethoxyphenyl22bipyridine5carbonitrile

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