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3,3′′-Bis(9-hy­droxy­fluoren-9-yl)-1,1′:3′,1′′-terphen­yl

The asymmetric unit of the title compound, C(44)H(30)O(2), contains two independent mol­ecules in which the terminal rings of the terphenyl element are inclined at angles of 36.3 (1) and 22.5 (1)° with respect to the central ring and the dihedral angles between the fluorenyl units are 72.3 (1) and 6...

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Autores principales: Skobridis, Konstantinos, Theodorou, Vassiliki, Paraskevopoulos, Georgios, Seichter, Wilhelm, Weber, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790384/
https://www.ncbi.nlm.nih.gov/pubmed/24098206
http://dx.doi.org/10.1107/S1600536813024033
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author Skobridis, Konstantinos
Theodorou, Vassiliki
Paraskevopoulos, Georgios
Seichter, Wilhelm
Weber, Edwin
author_facet Skobridis, Konstantinos
Theodorou, Vassiliki
Paraskevopoulos, Georgios
Seichter, Wilhelm
Weber, Edwin
author_sort Skobridis, Konstantinos
collection PubMed
description The asymmetric unit of the title compound, C(44)H(30)O(2), contains two independent mol­ecules in which the terminal rings of the terphenyl element are inclined at angles of 36.3 (1) and 22.5 (1)° with respect to the central ring and the dihedral angles between the fluorenyl units are 72.3 (1) and 62.8 (1)°. In the crystal, pairs of O—H⋯O hydrogen bonds link the mol­ecules into inversion dimers. The hy­droxy H atoms not involved in these hydrogen bonds form O—H⋯π inter­actions in which the central terphenyl rings act as acceptors. Weak C—H⋯O contacts and π–π [centroid–centroid distance = 4.088 (2) Å] stacking inter­actions also occur. Taking into account directed non-covalent bonding between the molecules, the crystal is constructed of supramolecular strands extending along the a-axis direction.
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spelling pubmed-37903842013-10-04 3,3′′-Bis(9-hy­droxy­fluoren-9-yl)-1,1′:3′,1′′-terphen­yl Skobridis, Konstantinos Theodorou, Vassiliki Paraskevopoulos, Georgios Seichter, Wilhelm Weber, Edwin Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(44)H(30)O(2), contains two independent mol­ecules in which the terminal rings of the terphenyl element are inclined at angles of 36.3 (1) and 22.5 (1)° with respect to the central ring and the dihedral angles between the fluorenyl units are 72.3 (1) and 62.8 (1)°. In the crystal, pairs of O—H⋯O hydrogen bonds link the mol­ecules into inversion dimers. The hy­droxy H atoms not involved in these hydrogen bonds form O—H⋯π inter­actions in which the central terphenyl rings act as acceptors. Weak C—H⋯O contacts and π–π [centroid–centroid distance = 4.088 (2) Å] stacking inter­actions also occur. Taking into account directed non-covalent bonding between the molecules, the crystal is constructed of supramolecular strands extending along the a-axis direction. International Union of Crystallography 2013-09-07 /pmc/articles/PMC3790384/ /pubmed/24098206 http://dx.doi.org/10.1107/S1600536813024033 Text en © Skobridis et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Skobridis, Konstantinos
Theodorou, Vassiliki
Paraskevopoulos, Georgios
Seichter, Wilhelm
Weber, Edwin
3,3′′-Bis(9-hy­droxy­fluoren-9-yl)-1,1′:3′,1′′-terphen­yl
title 3,3′′-Bis(9-hy­droxy­fluoren-9-yl)-1,1′:3′,1′′-terphen­yl
title_full 3,3′′-Bis(9-hy­droxy­fluoren-9-yl)-1,1′:3′,1′′-terphen­yl
title_fullStr 3,3′′-Bis(9-hy­droxy­fluoren-9-yl)-1,1′:3′,1′′-terphen­yl
title_full_unstemmed 3,3′′-Bis(9-hy­droxy­fluoren-9-yl)-1,1′:3′,1′′-terphen­yl
title_short 3,3′′-Bis(9-hy­droxy­fluoren-9-yl)-1,1′:3′,1′′-terphen­yl
title_sort 3,3′′-bis(9-hy­droxy­fluoren-9-yl)-1,1′:3′,1′′-terphen­yl
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790384/
https://www.ncbi.nlm.nih.gov/pubmed/24098206
http://dx.doi.org/10.1107/S1600536813024033
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