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3,3′′-Bis(9-hydroxyfluoren-9-yl)-1,1′:3′,1′′-terphenyl
The asymmetric unit of the title compound, C(44)H(30)O(2), contains two independent molecules in which the terminal rings of the terphenyl element are inclined at angles of 36.3 (1) and 22.5 (1)° with respect to the central ring and the dihedral angles between the fluorenyl units are 72.3 (1) and 6...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790384/ https://www.ncbi.nlm.nih.gov/pubmed/24098206 http://dx.doi.org/10.1107/S1600536813024033 |
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author | Skobridis, Konstantinos Theodorou, Vassiliki Paraskevopoulos, Georgios Seichter, Wilhelm Weber, Edwin |
author_facet | Skobridis, Konstantinos Theodorou, Vassiliki Paraskevopoulos, Georgios Seichter, Wilhelm Weber, Edwin |
author_sort | Skobridis, Konstantinos |
collection | PubMed |
description | The asymmetric unit of the title compound, C(44)H(30)O(2), contains two independent molecules in which the terminal rings of the terphenyl element are inclined at angles of 36.3 (1) and 22.5 (1)° with respect to the central ring and the dihedral angles between the fluorenyl units are 72.3 (1) and 62.8 (1)°. In the crystal, pairs of O—H⋯O hydrogen bonds link the molecules into inversion dimers. The hydroxy H atoms not involved in these hydrogen bonds form O—H⋯π interactions in which the central terphenyl rings act as acceptors. Weak C—H⋯O contacts and π–π [centroid–centroid distance = 4.088 (2) Å] stacking interactions also occur. Taking into account directed non-covalent bonding between the molecules, the crystal is constructed of supramolecular strands extending along the a-axis direction. |
format | Online Article Text |
id | pubmed-3790384 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903842013-10-04 3,3′′-Bis(9-hydroxyfluoren-9-yl)-1,1′:3′,1′′-terphenyl Skobridis, Konstantinos Theodorou, Vassiliki Paraskevopoulos, Georgios Seichter, Wilhelm Weber, Edwin Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(44)H(30)O(2), contains two independent molecules in which the terminal rings of the terphenyl element are inclined at angles of 36.3 (1) and 22.5 (1)° with respect to the central ring and the dihedral angles between the fluorenyl units are 72.3 (1) and 62.8 (1)°. In the crystal, pairs of O—H⋯O hydrogen bonds link the molecules into inversion dimers. The hydroxy H atoms not involved in these hydrogen bonds form O—H⋯π interactions in which the central terphenyl rings act as acceptors. Weak C—H⋯O contacts and π–π [centroid–centroid distance = 4.088 (2) Å] stacking interactions also occur. Taking into account directed non-covalent bonding between the molecules, the crystal is constructed of supramolecular strands extending along the a-axis direction. International Union of Crystallography 2013-09-07 /pmc/articles/PMC3790384/ /pubmed/24098206 http://dx.doi.org/10.1107/S1600536813024033 Text en © Skobridis et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Skobridis, Konstantinos Theodorou, Vassiliki Paraskevopoulos, Georgios Seichter, Wilhelm Weber, Edwin 3,3′′-Bis(9-hydroxyfluoren-9-yl)-1,1′:3′,1′′-terphenyl |
title | 3,3′′-Bis(9-hydroxyfluoren-9-yl)-1,1′:3′,1′′-terphenyl |
title_full | 3,3′′-Bis(9-hydroxyfluoren-9-yl)-1,1′:3′,1′′-terphenyl |
title_fullStr | 3,3′′-Bis(9-hydroxyfluoren-9-yl)-1,1′:3′,1′′-terphenyl |
title_full_unstemmed | 3,3′′-Bis(9-hydroxyfluoren-9-yl)-1,1′:3′,1′′-terphenyl |
title_short | 3,3′′-Bis(9-hydroxyfluoren-9-yl)-1,1′:3′,1′′-terphenyl |
title_sort | 3,3′′-bis(9-hydroxyfluoren-9-yl)-1,1′:3′,1′′-terphenyl |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790384/ https://www.ncbi.nlm.nih.gov/pubmed/24098206 http://dx.doi.org/10.1107/S1600536813024033 |
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