Dimethyl 3,3′-(phenyl­methyl­ene)bis­(1H-indole-2-carboxyl­ate)

In the title compound, C(27)H(22)N(2)O(4), the two indole ring systems are approximately perpendicular to each other, with a dihedral angle of 84.5 (5)° between their planes; the benzene ring is twisted with respect to the two indole ring systems at angles of 78.5 (5) and 86.5 (3)°. In the crystal,...

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Autores principales: Sun, Hong-Shun, Li, Yu-Long, Xu, Ning, Xu, Hong, Zhang, Ji-Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790385/
https://www.ncbi.nlm.nih.gov/pubmed/24098207
http://dx.doi.org/10.1107/S1600536813024471
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author Sun, Hong-Shun
Li, Yu-Long
Xu, Ning
Xu, Hong
Zhang, Ji-Dong
author_facet Sun, Hong-Shun
Li, Yu-Long
Xu, Ning
Xu, Hong
Zhang, Ji-Dong
author_sort Sun, Hong-Shun
collection PubMed
description In the title compound, C(27)H(22)N(2)O(4), the two indole ring systems are approximately perpendicular to each other, with a dihedral angle of 84.5 (5)° between their planes; the benzene ring is twisted with respect to the two indole ring systems at angles of 78.5 (5) and 86.5 (3)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, weak C—H⋯O and C—H⋯N hydrogen bonds, and C—H⋯π inter­actions into a three-dimensional supra­molecular architecture.
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spelling pubmed-37903852013-10-04 Dimethyl 3,3′-(phenyl­methyl­ene)bis­(1H-indole-2-carboxyl­ate) Sun, Hong-Shun Li, Yu-Long Xu, Ning Xu, Hong Zhang, Ji-Dong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(22)N(2)O(4), the two indole ring systems are approximately perpendicular to each other, with a dihedral angle of 84.5 (5)° between their planes; the benzene ring is twisted with respect to the two indole ring systems at angles of 78.5 (5) and 86.5 (3)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, weak C—H⋯O and C—H⋯N hydrogen bonds, and C—H⋯π inter­actions into a three-dimensional supra­molecular architecture. International Union of Crystallography 2013-09-07 /pmc/articles/PMC3790385/ /pubmed/24098207 http://dx.doi.org/10.1107/S1600536813024471 Text en © Sun et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Hong-Shun
Li, Yu-Long
Xu, Ning
Xu, Hong
Zhang, Ji-Dong
Dimethyl 3,3′-(phenyl­methyl­ene)bis­(1H-indole-2-carboxyl­ate)
title Dimethyl 3,3′-(phenyl­methyl­ene)bis­(1H-indole-2-carboxyl­ate)
title_full Dimethyl 3,3′-(phenyl­methyl­ene)bis­(1H-indole-2-carboxyl­ate)
title_fullStr Dimethyl 3,3′-(phenyl­methyl­ene)bis­(1H-indole-2-carboxyl­ate)
title_full_unstemmed Dimethyl 3,3′-(phenyl­methyl­ene)bis­(1H-indole-2-carboxyl­ate)
title_short Dimethyl 3,3′-(phenyl­methyl­ene)bis­(1H-indole-2-carboxyl­ate)
title_sort dimethyl 3,3′-(phenyl­methyl­ene)bis­(1h-indole-2-carboxyl­ate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790385/
https://www.ncbi.nlm.nih.gov/pubmed/24098207
http://dx.doi.org/10.1107/S1600536813024471
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AT xuning dimethyl33phenylmethylenebis1hindole2carboxylate
AT xuhong dimethyl33phenylmethylenebis1hindole2carboxylate
AT zhangjidong dimethyl33phenylmethylenebis1hindole2carboxylate

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