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2,3,4,5,6-Penta­fluoro-trans-cinnamic acid

The title compound, C(9)H(3)F(5)O(2), crystallizes as O—H⋯O hydrogen-bonded carb­oxy­lic acid dimers that, together with C—H⋯F inter­actions and O⋯F [2.8065 (13) and 2.9628 (13) Å] and F⋯F [2.6665 (11), 2.7049 (12) and 2.7314 (12) Å] contacts, form a sheet-like structure. The sheets are stacked via...

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Detalles Bibliográficos
Autores principales: Navarrete, Angélica, Somanathan, Ratnasamy, Aguirre, Gerardo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790387/
https://www.ncbi.nlm.nih.gov/pubmed/24098209
http://dx.doi.org/10.1107/S1600536813024513
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author Navarrete, Angélica
Somanathan, Ratnasamy
Aguirre, Gerardo
author_facet Navarrete, Angélica
Somanathan, Ratnasamy
Aguirre, Gerardo
author_sort Navarrete, Angélica
collection PubMed
description The title compound, C(9)H(3)F(5)O(2), crystallizes as O—H⋯O hydrogen-bonded carb­oxy­lic acid dimers that, together with C—H⋯F inter­actions and O⋯F [2.8065 (13) and 2.9628 (13) Å] and F⋯F [2.6665 (11), 2.7049 (12) and 2.7314 (12) Å] contacts, form a sheet-like structure. The sheets are stacked via short π–π inter­actions [centroid–centroid distance = 4.3198 (11) Å]. An intra­molecular C—H⋯F inter­action is also observed.
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spelling pubmed-37903872013-10-04 2,3,4,5,6-Penta­fluoro-trans-cinnamic acid Navarrete, Angélica Somanathan, Ratnasamy Aguirre, Gerardo Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(3)F(5)O(2), crystallizes as O—H⋯O hydrogen-bonded carb­oxy­lic acid dimers that, together with C—H⋯F inter­actions and O⋯F [2.8065 (13) and 2.9628 (13) Å] and F⋯F [2.6665 (11), 2.7049 (12) and 2.7314 (12) Å] contacts, form a sheet-like structure. The sheets are stacked via short π–π inter­actions [centroid–centroid distance = 4.3198 (11) Å]. An intra­molecular C—H⋯F inter­action is also observed. International Union of Crystallography 2013-09-07 /pmc/articles/PMC3790387/ /pubmed/24098209 http://dx.doi.org/10.1107/S1600536813024513 Text en © Navarrete et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Navarrete, Angélica
Somanathan, Ratnasamy
Aguirre, Gerardo
2,3,4,5,6-Penta­fluoro-trans-cinnamic acid
title 2,3,4,5,6-Penta­fluoro-trans-cinnamic acid
title_full 2,3,4,5,6-Penta­fluoro-trans-cinnamic acid
title_fullStr 2,3,4,5,6-Penta­fluoro-trans-cinnamic acid
title_full_unstemmed 2,3,4,5,6-Penta­fluoro-trans-cinnamic acid
title_short 2,3,4,5,6-Penta­fluoro-trans-cinnamic acid
title_sort 2,3,4,5,6-penta­fluoro-trans-cinnamic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790387/
https://www.ncbi.nlm.nih.gov/pubmed/24098209
http://dx.doi.org/10.1107/S1600536813024513
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