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2,3,4,5,6-Pentafluoro-trans-cinnamic acid
The title compound, C(9)H(3)F(5)O(2), crystallizes as O—H⋯O hydrogen-bonded carboxylic acid dimers that, together with C—H⋯F interactions and O⋯F [2.8065 (13) and 2.9628 (13) Å] and F⋯F [2.6665 (11), 2.7049 (12) and 2.7314 (12) Å] contacts, form a sheet-like structure. The sheets are stacked via...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790387/ https://www.ncbi.nlm.nih.gov/pubmed/24098209 http://dx.doi.org/10.1107/S1600536813024513 |
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author | Navarrete, Angélica Somanathan, Ratnasamy Aguirre, Gerardo |
author_facet | Navarrete, Angélica Somanathan, Ratnasamy Aguirre, Gerardo |
author_sort | Navarrete, Angélica |
collection | PubMed |
description | The title compound, C(9)H(3)F(5)O(2), crystallizes as O—H⋯O hydrogen-bonded carboxylic acid dimers that, together with C—H⋯F interactions and O⋯F [2.8065 (13) and 2.9628 (13) Å] and F⋯F [2.6665 (11), 2.7049 (12) and 2.7314 (12) Å] contacts, form a sheet-like structure. The sheets are stacked via short π–π interactions [centroid–centroid distance = 4.3198 (11) Å]. An intramolecular C—H⋯F interaction is also observed. |
format | Online Article Text |
id | pubmed-3790387 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903872013-10-04 2,3,4,5,6-Pentafluoro-trans-cinnamic acid Navarrete, Angélica Somanathan, Ratnasamy Aguirre, Gerardo Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(3)F(5)O(2), crystallizes as O—H⋯O hydrogen-bonded carboxylic acid dimers that, together with C—H⋯F interactions and O⋯F [2.8065 (13) and 2.9628 (13) Å] and F⋯F [2.6665 (11), 2.7049 (12) and 2.7314 (12) Å] contacts, form a sheet-like structure. The sheets are stacked via short π–π interactions [centroid–centroid distance = 4.3198 (11) Å]. An intramolecular C—H⋯F interaction is also observed. International Union of Crystallography 2013-09-07 /pmc/articles/PMC3790387/ /pubmed/24098209 http://dx.doi.org/10.1107/S1600536813024513 Text en © Navarrete et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Navarrete, Angélica Somanathan, Ratnasamy Aguirre, Gerardo 2,3,4,5,6-Pentafluoro-trans-cinnamic acid |
title | 2,3,4,5,6-Pentafluoro-trans-cinnamic acid |
title_full | 2,3,4,5,6-Pentafluoro-trans-cinnamic acid |
title_fullStr | 2,3,4,5,6-Pentafluoro-trans-cinnamic acid |
title_full_unstemmed | 2,3,4,5,6-Pentafluoro-trans-cinnamic acid |
title_short | 2,3,4,5,6-Pentafluoro-trans-cinnamic acid |
title_sort | 2,3,4,5,6-pentafluoro-trans-cinnamic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790387/ https://www.ncbi.nlm.nih.gov/pubmed/24098209 http://dx.doi.org/10.1107/S1600536813024513 |
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