N-(2-Fluoro­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine

In the title compound, C(12)H(16)FNO(3), the dioxane ring adopts a chair conformation with the methyl groups and amine N atom in equatorial positions. The best plane through the dioxane ring makes a dihedral angle of 43.16 (8)° with the phenyl ring. In the crystal, pairs of C—H⋯O hydrogen bonds link...

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Autores principales: Fatima, Zeenat, Rambabu, Gottimukkala, Reddy, Bandapalli Palakshi, Vijayakumar, Vijayaparthasarathi, Velmurugan, Devadasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790394/
https://www.ncbi.nlm.nih.gov/pubmed/24098213
http://dx.doi.org/10.1107/S1600536813024732
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author Fatima, Zeenat
Rambabu, Gottimukkala
Reddy, Bandapalli Palakshi
Vijayakumar, Vijayaparthasarathi
Velmurugan, Devadasan
author_facet Fatima, Zeenat
Rambabu, Gottimukkala
Reddy, Bandapalli Palakshi
Vijayakumar, Vijayaparthasarathi
Velmurugan, Devadasan
author_sort Fatima, Zeenat
collection PubMed
description In the title compound, C(12)H(16)FNO(3), the dioxane ring adopts a chair conformation with the methyl groups and amine N atom in equatorial positions. The best plane through the dioxane ring makes a dihedral angle of 43.16 (8)° with the phenyl ring. In the crystal, pairs of C—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric R (2) (2)(8) dimers, which are linked into [100] chains by further C—H⋯O hydrogen bonds. The N—H group does not participate in hydrogen bonding.
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spelling pubmed-37903942013-10-04 N-(2-Fluoro­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine Fatima, Zeenat Rambabu, Gottimukkala Reddy, Bandapalli Palakshi Vijayakumar, Vijayaparthasarathi Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(16)FNO(3), the dioxane ring adopts a chair conformation with the methyl groups and amine N atom in equatorial positions. The best plane through the dioxane ring makes a dihedral angle of 43.16 (8)° with the phenyl ring. In the crystal, pairs of C—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric R (2) (2)(8) dimers, which are linked into [100] chains by further C—H⋯O hydrogen bonds. The N—H group does not participate in hydrogen bonding. International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790394/ /pubmed/24098213 http://dx.doi.org/10.1107/S1600536813024732 Text en © Fatima et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fatima, Zeenat
Rambabu, Gottimukkala
Reddy, Bandapalli Palakshi
Vijayakumar, Vijayaparthasarathi
Velmurugan, Devadasan
N-(2-Fluoro­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title N-(2-Fluoro­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_full N-(2-Fluoro­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_fullStr N-(2-Fluoro­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_full_unstemmed N-(2-Fluoro­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_short N-(2-Fluoro­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_sort n-(2-fluoro­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790394/
https://www.ncbi.nlm.nih.gov/pubmed/24098213
http://dx.doi.org/10.1107/S1600536813024732
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