2,4-Bis(4-fluoro­phen­yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one

The asymmetric unit of the title compound, C(22)H(23)F(2)NO, contains two independent mol­ecules, A and B. The bicyclic system adopts a twin-chair conformation in both mol­ecules. The dihedral angles between the fluoro­phenyl rings are 55.27 (8) and 56.37 (7)° in mol­ecules A and B, respectively. Th...

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Autores principales: Rizwana Begum, S., Hema, R., Venkateswaramoorthi, R., Krishnasamy, K., Anitha, A. G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790395/
https://www.ncbi.nlm.nih.gov/pubmed/24098214
http://dx.doi.org/10.1107/S1600536813024689
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author Rizwana Begum, S.
Hema, R.
Venkateswaramoorthi, R.
Krishnasamy, K.
Anitha, A. G.
author_facet Rizwana Begum, S.
Hema, R.
Venkateswaramoorthi, R.
Krishnasamy, K.
Anitha, A. G.
author_sort Rizwana Begum, S.
collection PubMed
description The asymmetric unit of the title compound, C(22)H(23)F(2)NO, contains two independent mol­ecules, A and B. The bicyclic system adopts a twin-chair conformation in both mol­ecules. The dihedral angles between the fluoro­phenyl rings are 55.27 (8) and 56.37 (7)° in mol­ecules A and B, respectively. The NH groups are not involved in hydrogen bonding due to the steric hindrance of fluoro­phenyl groups. The crystal structure features weak C—H⋯O inter­actions.
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spelling pubmed-37903952013-10-04 2,4-Bis(4-fluoro­phen­yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one Rizwana Begum, S. Hema, R. Venkateswaramoorthi, R. Krishnasamy, K. Anitha, A. G. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(22)H(23)F(2)NO, contains two independent mol­ecules, A and B. The bicyclic system adopts a twin-chair conformation in both mol­ecules. The dihedral angles between the fluoro­phenyl rings are 55.27 (8) and 56.37 (7)° in mol­ecules A and B, respectively. The NH groups are not involved in hydrogen bonding due to the steric hindrance of fluoro­phenyl groups. The crystal structure features weak C—H⋯O inter­actions. International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790395/ /pubmed/24098214 http://dx.doi.org/10.1107/S1600536813024689 Text en © Rizwana Begum et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rizwana Begum, S.
Hema, R.
Venkateswaramoorthi, R.
Krishnasamy, K.
Anitha, A. G.
2,4-Bis(4-fluoro­phen­yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title 2,4-Bis(4-fluoro­phen­yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full 2,4-Bis(4-fluoro­phen­yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_fullStr 2,4-Bis(4-fluoro­phen­yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full_unstemmed 2,4-Bis(4-fluoro­phen­yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_short 2,4-Bis(4-fluoro­phen­yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_sort 2,4-bis(4-fluoro­phen­yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790395/
https://www.ncbi.nlm.nih.gov/pubmed/24098214
http://dx.doi.org/10.1107/S1600536813024689
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