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2-Dichloromethyl-N-ethyl-5-(1-phenylsilolan-1-yl)cyclopent-3-enecarboxamide
In the title compound, C(19)H(25)Cl(2)NOSi, the NH group and the carbonyl O atom of the amide fragment are involved in an intermolecular N—H⋯O hydrogen bond forming chains of molecules. The plane of the benzene ring forms a dihedral angle of 50.5 (2)° with respect to the silolane ring and an angle...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790399/ https://www.ncbi.nlm.nih.gov/pubmed/24098218 http://dx.doi.org/10.1107/S160053681302446X |
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author | Xiao, Han Yang, Wan-Qiu Shen, Liang |
author_facet | Xiao, Han Yang, Wan-Qiu Shen, Liang |
author_sort | Xiao, Han |
collection | PubMed |
description | In the title compound, C(19)H(25)Cl(2)NOSi, the NH group and the carbonyl O atom of the amide fragment are involved in an intermolecular N—H⋯O hydrogen bond forming chains of molecules. The plane of the benzene ring forms a dihedral angle of 50.5 (2)° with respect to the silolane ring and an angle of 49.74 (2)° with the cyclopentyl moiety. |
format | Online Article Text |
id | pubmed-3790399 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37903992013-10-04 2-Dichloromethyl-N-ethyl-5-(1-phenylsilolan-1-yl)cyclopent-3-enecarboxamide Xiao, Han Yang, Wan-Qiu Shen, Liang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(25)Cl(2)NOSi, the NH group and the carbonyl O atom of the amide fragment are involved in an intermolecular N—H⋯O hydrogen bond forming chains of molecules. The plane of the benzene ring forms a dihedral angle of 50.5 (2)° with respect to the silolane ring and an angle of 49.74 (2)° with the cyclopentyl moiety. International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790399/ /pubmed/24098218 http://dx.doi.org/10.1107/S160053681302446X Text en © Xiao et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Xiao, Han Yang, Wan-Qiu Shen, Liang 2-Dichloromethyl-N-ethyl-5-(1-phenylsilolan-1-yl)cyclopent-3-enecarboxamide |
title | 2-Dichloromethyl-N-ethyl-5-(1-phenylsilolan-1-yl)cyclopent-3-enecarboxamide |
title_full | 2-Dichloromethyl-N-ethyl-5-(1-phenylsilolan-1-yl)cyclopent-3-enecarboxamide |
title_fullStr | 2-Dichloromethyl-N-ethyl-5-(1-phenylsilolan-1-yl)cyclopent-3-enecarboxamide |
title_full_unstemmed | 2-Dichloromethyl-N-ethyl-5-(1-phenylsilolan-1-yl)cyclopent-3-enecarboxamide |
title_short | 2-Dichloromethyl-N-ethyl-5-(1-phenylsilolan-1-yl)cyclopent-3-enecarboxamide |
title_sort | 2-dichloromethyl-n-ethyl-5-(1-phenylsilolan-1-yl)cyclopent-3-enecarboxamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790399/ https://www.ncbi.nlm.nih.gov/pubmed/24098218 http://dx.doi.org/10.1107/S160053681302446X |
work_keys_str_mv | AT xiaohan 2dichloromethylnethyl51phenylsilolan1ylcyclopent3enecarboxamide AT yangwanqiu 2dichloromethylnethyl51phenylsilolan1ylcyclopent3enecarboxamide AT shenliang 2dichloromethylnethyl51phenylsilolan1ylcyclopent3enecarboxamide |