N-(2-Methyl­phen­yl)-1,2-benzoselen­azol-3(2H)-one

In the title Ebselen [systematic name: (2-phenyl-1,2-benzoisoselenazol-3-(2H)-one)] analogue, C(14)H(11)NOSe, the benzisoselenazolyl moiety (r.m.s. deviation = 0.0209 Å) is nearly perpendicular to the N-arenyl ring, making a dihedral angle of 78.15 (11)°. In the crystal, mol­ecules are linked by C—H...

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Autores principales: Zhu, Xu, Xu, Ying, Han, Hongfei, Guo, Zhiqiang, Wei, Xuehong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790406/
https://www.ncbi.nlm.nih.gov/pubmed/24098225
http://dx.doi.org/10.1107/S1600536813024744
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author Zhu, Xu
Xu, Ying
Han, Hongfei
Guo, Zhiqiang
Wei, Xuehong
author_facet Zhu, Xu
Xu, Ying
Han, Hongfei
Guo, Zhiqiang
Wei, Xuehong
author_sort Zhu, Xu
collection PubMed
description In the title Ebselen [systematic name: (2-phenyl-1,2-benzoisoselenazol-3-(2H)-one)] analogue, C(14)H(11)NOSe, the benzisoselenazolyl moiety (r.m.s. deviation = 0.0209 Å) is nearly perpendicular to the N-arenyl ring, making a dihedral angle of 78.15 (11)°. In the crystal, mol­ecules are linked by C—H⋯O and Se⋯O inter­actions into chains along the c-axis direction. The Se⋯O distance [2.733 (3) Å] is longer than that in Ebselen (2.571 (3) Å].
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spelling pubmed-37904062013-10-04 N-(2-Methyl­phen­yl)-1,2-benzoselen­azol-3(2H)-one Zhu, Xu Xu, Ying Han, Hongfei Guo, Zhiqiang Wei, Xuehong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Ebselen [systematic name: (2-phenyl-1,2-benzoisoselenazol-3-(2H)-one)] analogue, C(14)H(11)NOSe, the benzisoselenazolyl moiety (r.m.s. deviation = 0.0209 Å) is nearly perpendicular to the N-arenyl ring, making a dihedral angle of 78.15 (11)°. In the crystal, mol­ecules are linked by C—H⋯O and Se⋯O inter­actions into chains along the c-axis direction. The Se⋯O distance [2.733 (3) Å] is longer than that in Ebselen (2.571 (3) Å]. International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790406/ /pubmed/24098225 http://dx.doi.org/10.1107/S1600536813024744 Text en © Zhu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhu, Xu
Xu, Ying
Han, Hongfei
Guo, Zhiqiang
Wei, Xuehong
N-(2-Methyl­phen­yl)-1,2-benzoselen­azol-3(2H)-one
title N-(2-Methyl­phen­yl)-1,2-benzoselen­azol-3(2H)-one
title_full N-(2-Methyl­phen­yl)-1,2-benzoselen­azol-3(2H)-one
title_fullStr N-(2-Methyl­phen­yl)-1,2-benzoselen­azol-3(2H)-one
title_full_unstemmed N-(2-Methyl­phen­yl)-1,2-benzoselen­azol-3(2H)-one
title_short N-(2-Methyl­phen­yl)-1,2-benzoselen­azol-3(2H)-one
title_sort n-(2-methyl­phen­yl)-1,2-benzoselen­azol-3(2h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790406/
https://www.ncbi.nlm.nih.gov/pubmed/24098225
http://dx.doi.org/10.1107/S1600536813024744
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