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5-Chloro-2-(thio­phen-2-yl)-1-(thio­phen-2-ylmeth­yl)-1H-benzimidazole–6-chloro-2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole (0.94/0.06)

There are two independent mol­ecules in the asymmetric unit of the title compound, C(16)H(11)ClN(2)S(2). The structure exhibits rotational disorder of the 2-thio­phen-2-yl substituent in each of the unique mol­ecules with a major:minor component ratio of 0.927 (2):0.073 (2). For one of the symmetry-...

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Detalles Bibliográficos
Autores principales: Geiger, David K., Nellist, Michael R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790407/
https://www.ncbi.nlm.nih.gov/pubmed/24098226
http://dx.doi.org/10.1107/S1600536813024999
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author Geiger, David K.
Nellist, Michael R.
author_facet Geiger, David K.
Nellist, Michael R.
author_sort Geiger, David K.
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(16)H(11)ClN(2)S(2). The structure exhibits rotational disorder of the 2-thio­phen-2-yl substituent in each of the unique mol­ecules with a major:minor component ratio of 0.927 (2):0.073 (2). For one of the symmetry-unique molecules, 6.0 (2)% of the sites are occupied by the 6-chloro-isomer. The major component thio­phene rings make dihedral angles of 38.90 (12) and 36.32 (11)° with the benzimidazole rings in the two independent mol­ecules. In the crystal, mol­ecules are linked into chains parallel to [100] via weak C—H⋯N inter­actions.
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spelling pubmed-37904072013-10-04 5-Chloro-2-(thio­phen-2-yl)-1-(thio­phen-2-ylmeth­yl)-1H-benzimidazole–6-chloro-2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole (0.94/0.06) Geiger, David K. Nellist, Michael R. Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(16)H(11)ClN(2)S(2). The structure exhibits rotational disorder of the 2-thio­phen-2-yl substituent in each of the unique mol­ecules with a major:minor component ratio of 0.927 (2):0.073 (2). For one of the symmetry-unique molecules, 6.0 (2)% of the sites are occupied by the 6-chloro-isomer. The major component thio­phene rings make dihedral angles of 38.90 (12) and 36.32 (11)° with the benzimidazole rings in the two independent mol­ecules. In the crystal, mol­ecules are linked into chains parallel to [100] via weak C—H⋯N inter­actions. International Union of Crystallography 2013-09-12 /pmc/articles/PMC3790407/ /pubmed/24098226 http://dx.doi.org/10.1107/S1600536813024999 Text en © Geiger and Nellist 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Geiger, David K.
Nellist, Michael R.
5-Chloro-2-(thio­phen-2-yl)-1-(thio­phen-2-ylmeth­yl)-1H-benzimidazole–6-chloro-2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole (0.94/0.06)
title 5-Chloro-2-(thio­phen-2-yl)-1-(thio­phen-2-ylmeth­yl)-1H-benzimidazole–6-chloro-2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole (0.94/0.06)
title_full 5-Chloro-2-(thio­phen-2-yl)-1-(thio­phen-2-ylmeth­yl)-1H-benzimidazole–6-chloro-2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole (0.94/0.06)
title_fullStr 5-Chloro-2-(thio­phen-2-yl)-1-(thio­phen-2-ylmeth­yl)-1H-benzimidazole–6-chloro-2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole (0.94/0.06)
title_full_unstemmed 5-Chloro-2-(thio­phen-2-yl)-1-(thio­phen-2-ylmeth­yl)-1H-benzimidazole–6-chloro-2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole (0.94/0.06)
title_short 5-Chloro-2-(thio­phen-2-yl)-1-(thio­phen-2-ylmeth­yl)-1H-benzimidazole–6-chloro-2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole (0.94/0.06)
title_sort 5-chloro-2-(thio­phen-2-yl)-1-(thio­phen-2-ylmeth­yl)-1h-benzimidazole–6-chloro-2-(thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1h-benzimidazole (0.94/0.06)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790407/
https://www.ncbi.nlm.nih.gov/pubmed/24098226
http://dx.doi.org/10.1107/S1600536813024999
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