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Amino­[(1H-benzimidazol-2-yl)amino]­methaniminium 4-methyl­benzene­sulfonate

The asymmetric unit of the title salt, C(8)H(10)N(5) (+)·C(7)H(7)O(3)S(−), consists of two amino­[(1H-benzimidazol-2-yl)amino]­meth­an­im­inium cations and two 4-methyl­benzene­sulfonate anions. The cations are each stabilized by intra­molecular N—H⋯N hydrogen bonds between the free amino groups and...

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Detalles Bibliográficos
Autores principales: Mohamed, Shaaban K., Akkurt, Mehmet, Elremaily, Mahmoud A. A., Ali, Ali. M., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790410/
https://www.ncbi.nlm.nih.gov/pubmed/24098229
http://dx.doi.org/10.1107/S1600536813024975
Descripción
Sumario:The asymmetric unit of the title salt, C(8)H(10)N(5) (+)·C(7)H(7)O(3)S(−), consists of two amino­[(1H-benzimidazol-2-yl)amino]­meth­an­im­inium cations and two 4-methyl­benzene­sulfonate anions. The cations are each stabilized by intra­molecular N—H⋯N hydrogen bonds between the free amino groups and the imine N atoms of the benzimidazole units, forming S(6) ring motifs. In the crystal, cations and anions are linked by N—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular framework. Two strong π–π stacking inter­actions [centroid–centroid distances = 3.4112 (14) and 3.4104 (14) Å] also occur between the centroids of the imidazole rings of like cations.