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4-{(E)-[2-(Pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate
The title compound, C(15)H(13)N(3)O(3), exists in the E conformation with respect to the azomethane C=N double bond. The pyridyl and phenyl rings form dihedral angles of 35.67 (8) and 36.65 (7)°, respectively with the central C(=O)N(2)C unit. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds connect t...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790414/ https://www.ncbi.nlm.nih.gov/pubmed/24098233 http://dx.doi.org/10.1107/S1600536813025075 |
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author | Datta, Riya Ramya, V. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_facet | Datta, Riya Ramya, V. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_sort | Datta, Riya |
collection | PubMed |
description | The title compound, C(15)H(13)N(3)O(3), exists in the E conformation with respect to the azomethane C=N double bond. The pyridyl and phenyl rings form dihedral angles of 35.67 (8) and 36.65 (7)°, respectively with the central C(=O)N(2)C unit. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds connect the molecules into chains along the b axis. Another C—H⋯O interaction connects molecules along the c-axis direction, forming layers. |
format | Online Article Text |
id | pubmed-3790414 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37904142013-10-04 4-{(E)-[2-(Pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate Datta, Riya Ramya, V. Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(13)N(3)O(3), exists in the E conformation with respect to the azomethane C=N double bond. The pyridyl and phenyl rings form dihedral angles of 35.67 (8) and 36.65 (7)°, respectively with the central C(=O)N(2)C unit. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds connect the molecules into chains along the b axis. Another C—H⋯O interaction connects molecules along the c-axis direction, forming layers. International Union of Crystallography 2013-09-18 /pmc/articles/PMC3790414/ /pubmed/24098233 http://dx.doi.org/10.1107/S1600536813025075 Text en © Datta et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Datta, Riya Ramya, V. Sithambaresan, M. Kurup, M. R. Prathapachandra 4-{(E)-[2-(Pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate |
title | 4-{(E)-[2-(Pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate |
title_full | 4-{(E)-[2-(Pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate |
title_fullStr | 4-{(E)-[2-(Pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate |
title_full_unstemmed | 4-{(E)-[2-(Pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate |
title_short | 4-{(E)-[2-(Pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate |
title_sort | 4-{(e)-[2-(pyridin-3-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790414/ https://www.ncbi.nlm.nih.gov/pubmed/24098233 http://dx.doi.org/10.1107/S1600536813025075 |
work_keys_str_mv | AT dattariya 4e2pyridin3ylcarbonylhydrazinylidenemethylphenylacetate AT ramyav 4e2pyridin3ylcarbonylhydrazinylidenemethylphenylacetate AT sithambaresanm 4e2pyridin3ylcarbonylhydrazinylidenemethylphenylacetate AT kurupmrprathapachandra 4e2pyridin3ylcarbonylhydrazinylidenemethylphenylacetate |