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Methyl 2-((2Z,5Z)-2-{(E)-2-[1-(4-hydroxyphenyl)ethylidene]hydrazin-1-ylidene}-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene)acetate
In the title compound, C(20)H(17)N(3)O(4)S, all non-H atoms, except those of the phenyl ring, are approximately coplanar [maximum deviation = 0.2214 (1) Å], and the dihedral angle between their best plane and the benzene ring is 53.13 (1)°. A short intramolecular O⋯S contact of 2.838 (1) Å is forme...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790417/ https://www.ncbi.nlm.nih.gov/pubmed/24098236 http://dx.doi.org/10.1107/S1600536813025270 |
Sumario: | In the title compound, C(20)H(17)N(3)O(4)S, all non-H atoms, except those of the phenyl ring, are approximately coplanar [maximum deviation = 0.2214 (1) Å], and the dihedral angle between their best plane and the benzene ring is 53.13 (1)°. A short intramolecular O⋯S contact of 2.838 (1) Å is formed between the ester carbonyl O atom and the S atom of the thiazolidine ring. In the crystal, molecules associated via O—H⋯O, C—H⋯O and C—H⋯S hydrogen bonds form layers parallel to (010), with only C—H⋯O-type short contacts between the molecules in adjacent layers. |
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