Methyl 2-((2Z,5Z)-2-{(E)-2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)acetate

In the title compound, C(20)H(17)N(3)O(4)S, all non-H atoms, except those of the phenyl ring, are approximately coplanar [maximum deviation = 0.2214 (1) Å], and the dihedral angle between their best plane and the benzene ring is 53.13 (1)°. A short intra­molecular O⋯S contact of 2.838 (1) Å is forme...

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Autores principales: Mohamed, Shaaban K., Mague, Joel T., Akkurt, Mehmet, Hassan, Alaa A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790417/
https://www.ncbi.nlm.nih.gov/pubmed/24098236
http://dx.doi.org/10.1107/S1600536813025270
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author Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Hassan, Alaa A.
Albayati, Mustafa R.
author_facet Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Hassan, Alaa A.
Albayati, Mustafa R.
author_sort Mohamed, Shaaban K.
collection PubMed
description In the title compound, C(20)H(17)N(3)O(4)S, all non-H atoms, except those of the phenyl ring, are approximately coplanar [maximum deviation = 0.2214 (1) Å], and the dihedral angle between their best plane and the benzene ring is 53.13 (1)°. A short intra­molecular O⋯S contact of 2.838 (1) Å is formed between the ester carbonyl O atom and the S atom of the thia­zolidine ring. In the crystal, mol­ecules associated via O—H⋯O, C—H⋯O and C—H⋯S hydrogen bonds form layers parallel to (010), with only C—H⋯O-type short contacts between the mol­ecules in adjacent layers.
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spelling pubmed-37904172013-10-04 Methyl 2-((2Z,5Z)-2-{(E)-2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)acetate Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Hassan, Alaa A. Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(17)N(3)O(4)S, all non-H atoms, except those of the phenyl ring, are approximately coplanar [maximum deviation = 0.2214 (1) Å], and the dihedral angle between their best plane and the benzene ring is 53.13 (1)°. A short intra­molecular O⋯S contact of 2.838 (1) Å is formed between the ester carbonyl O atom and the S atom of the thia­zolidine ring. In the crystal, mol­ecules associated via O—H⋯O, C—H⋯O and C—H⋯S hydrogen bonds form layers parallel to (010), with only C—H⋯O-type short contacts between the mol­ecules in adjacent layers. International Union of Crystallography 2013-09-18 /pmc/articles/PMC3790417/ /pubmed/24098236 http://dx.doi.org/10.1107/S1600536813025270 Text en © Mohamed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Hassan, Alaa A.
Albayati, Mustafa R.
Methyl 2-((2Z,5Z)-2-{(E)-2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)acetate
title Methyl 2-((2Z,5Z)-2-{(E)-2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)acetate
title_full Methyl 2-((2Z,5Z)-2-{(E)-2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)acetate
title_fullStr Methyl 2-((2Z,5Z)-2-{(E)-2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)acetate
title_full_unstemmed Methyl 2-((2Z,5Z)-2-{(E)-2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)acetate
title_short Methyl 2-((2Z,5Z)-2-{(E)-2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)acetate
title_sort methyl 2-((2z,5z)-2-{(e)-2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790417/
https://www.ncbi.nlm.nih.gov/pubmed/24098236
http://dx.doi.org/10.1107/S1600536813025270
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AT albayatimustafar methyl22z5z2e214hydroxyphenylethylidenehydrazin1ylidene4oxo3phenyl13thiazolidin5ylideneacetate

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