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12-(2-Hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8H-benzo[a]xanthen-11(12H)-one

In the xanthenone system of the title compound, C(23)H(20)O(4), the pyran ring has a maximum deviation of 0.111 (1) Å from planarity and the outer cyclo­hexene ring exhibits a puckered conformation. The three methyl­ene C atoms of the cyclo­hexene ring bonded to the pyran unit are disordered over tw...

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Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Mohamed, Shaaban K., Kennedy, Alan R., Abdelhamid, Antar A., Miller, Gary J., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790420/
https://www.ncbi.nlm.nih.gov/pubmed/24098239
http://dx.doi.org/10.1107/S1600536813025324
Descripción
Sumario:In the xanthenone system of the title compound, C(23)H(20)O(4), the pyran ring has a maximum deviation of 0.111 (1) Å from planarity and the outer cyclo­hexene ring exhibits a puckered conformation. The three methyl­ene C atoms of the cyclo­hexene ring bonded to the pyran unit are disordered over two sets of sites [occupancies = 0.570 (3) and 0.430 (3)]. In the crystal, mol­ecules are linked by C—H⋯O and O—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (110). A C—H⋯π inter­action occurs between these networks.