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12-(2-Hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one
In the xanthenone system of the title compound, C(23)H(20)O(4), the pyran ring has a maximum deviation of 0.111 (1) Å from planarity and the outer cyclohexene ring exhibits a puckered conformation. The three methylene C atoms of the cyclohexene ring bonded to the pyran unit are disordered over tw...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790420/ https://www.ncbi.nlm.nih.gov/pubmed/24098239 http://dx.doi.org/10.1107/S1600536813025324 |
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author | Akkurt, Mehmet Mohamed, Shaaban K. Kennedy, Alan R. Abdelhamid, Antar A. Miller, Gary J. Albayati, Mustafa R. |
author_facet | Akkurt, Mehmet Mohamed, Shaaban K. Kennedy, Alan R. Abdelhamid, Antar A. Miller, Gary J. Albayati, Mustafa R. |
author_sort | Akkurt, Mehmet |
collection | PubMed |
description | In the xanthenone system of the title compound, C(23)H(20)O(4), the pyran ring has a maximum deviation of 0.111 (1) Å from planarity and the outer cyclohexene ring exhibits a puckered conformation. The three methylene C atoms of the cyclohexene ring bonded to the pyran unit are disordered over two sets of sites [occupancies = 0.570 (3) and 0.430 (3)]. In the crystal, molecules are linked by C—H⋯O and O—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (110). A C—H⋯π interaction occurs between these networks. |
format | Online Article Text |
id | pubmed-3790420 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37904202013-10-04 12-(2-Hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one Akkurt, Mehmet Mohamed, Shaaban K. Kennedy, Alan R. Abdelhamid, Antar A. Miller, Gary J. Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the xanthenone system of the title compound, C(23)H(20)O(4), the pyran ring has a maximum deviation of 0.111 (1) Å from planarity and the outer cyclohexene ring exhibits a puckered conformation. The three methylene C atoms of the cyclohexene ring bonded to the pyran unit are disordered over two sets of sites [occupancies = 0.570 (3) and 0.430 (3)]. In the crystal, molecules are linked by C—H⋯O and O—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (110). A C—H⋯π interaction occurs between these networks. International Union of Crystallography 2013-09-18 /pmc/articles/PMC3790420/ /pubmed/24098239 http://dx.doi.org/10.1107/S1600536813025324 Text en © Akkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Akkurt, Mehmet Mohamed, Shaaban K. Kennedy, Alan R. Abdelhamid, Antar A. Miller, Gary J. Albayati, Mustafa R. 12-(2-Hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one |
title | 12-(2-Hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one |
title_full | 12-(2-Hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one |
title_fullStr | 12-(2-Hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one |
title_full_unstemmed | 12-(2-Hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one |
title_short | 12-(2-Hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one |
title_sort | 12-(2-hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8h-benzo[a]xanthen-11(12h)-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790420/ https://www.ncbi.nlm.nih.gov/pubmed/24098239 http://dx.doi.org/10.1107/S1600536813025324 |
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