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12-(2-Hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8H-benzo[a]xanthen-11(12H)-one

In the xanthenone system of the title compound, C(23)H(20)O(4), the pyran ring has a maximum deviation of 0.111 (1) Å from planarity and the outer cyclo­hexene ring exhibits a puckered conformation. The three methyl­ene C atoms of the cyclo­hexene ring bonded to the pyran unit are disordered over tw...

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Autores principales: Akkurt, Mehmet, Mohamed, Shaaban K., Kennedy, Alan R., Abdelhamid, Antar A., Miller, Gary J., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790420/
https://www.ncbi.nlm.nih.gov/pubmed/24098239
http://dx.doi.org/10.1107/S1600536813025324
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author Akkurt, Mehmet
Mohamed, Shaaban K.
Kennedy, Alan R.
Abdelhamid, Antar A.
Miller, Gary J.
Albayati, Mustafa R.
author_facet Akkurt, Mehmet
Mohamed, Shaaban K.
Kennedy, Alan R.
Abdelhamid, Antar A.
Miller, Gary J.
Albayati, Mustafa R.
author_sort Akkurt, Mehmet
collection PubMed
description In the xanthenone system of the title compound, C(23)H(20)O(4), the pyran ring has a maximum deviation of 0.111 (1) Å from planarity and the outer cyclo­hexene ring exhibits a puckered conformation. The three methyl­ene C atoms of the cyclo­hexene ring bonded to the pyran unit are disordered over two sets of sites [occupancies = 0.570 (3) and 0.430 (3)]. In the crystal, mol­ecules are linked by C—H⋯O and O—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (110). A C—H⋯π inter­action occurs between these networks.
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spelling pubmed-37904202013-10-04 12-(2-Hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8H-benzo[a]xanthen-11(12H)-one Akkurt, Mehmet Mohamed, Shaaban K. Kennedy, Alan R. Abdelhamid, Antar A. Miller, Gary J. Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the xanthenone system of the title compound, C(23)H(20)O(4), the pyran ring has a maximum deviation of 0.111 (1) Å from planarity and the outer cyclo­hexene ring exhibits a puckered conformation. The three methyl­ene C atoms of the cyclo­hexene ring bonded to the pyran unit are disordered over two sets of sites [occupancies = 0.570 (3) and 0.430 (3)]. In the crystal, mol­ecules are linked by C—H⋯O and O—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (110). A C—H⋯π inter­action occurs between these networks. International Union of Crystallography 2013-09-18 /pmc/articles/PMC3790420/ /pubmed/24098239 http://dx.doi.org/10.1107/S1600536813025324 Text en © Akkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Mohamed, Shaaban K.
Kennedy, Alan R.
Abdelhamid, Antar A.
Miller, Gary J.
Albayati, Mustafa R.
12-(2-Hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8H-benzo[a]xanthen-11(12H)-one
title 12-(2-Hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8H-benzo[a]xanthen-11(12H)-one
title_full 12-(2-Hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8H-benzo[a]xanthen-11(12H)-one
title_fullStr 12-(2-Hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8H-benzo[a]xanthen-11(12H)-one
title_full_unstemmed 12-(2-Hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8H-benzo[a]xanthen-11(12H)-one
title_short 12-(2-Hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8H-benzo[a]xanthen-11(12H)-one
title_sort 12-(2-hy­droxy-6-oxo­cyclo­hex-1-en­yl)-9,10-di­hydro-8h-benzo[a]xanthen-11(12h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790420/
https://www.ncbi.nlm.nih.gov/pubmed/24098239
http://dx.doi.org/10.1107/S1600536813025324
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