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5,6-Dimethyl-1,10-phenanthroline
In the title compound, C(14)H(12)N(2), the N⋯N distance is 2.719 (1) Å. The N—C—C—N torsion angle [0.9 (1)°] is close to the ideal value of 0° as expected. Bond lengths and angles are consistent with those observed for [1,10]phenanthroline and coordinated 5,6 dimethyl[1,10]phenanthroline. In the cr...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790421/ https://www.ncbi.nlm.nih.gov/pubmed/24098240 http://dx.doi.org/10.1107/S1600536813025087 |
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author | Rozenel, Sergio S. |
author_facet | Rozenel, Sergio S. |
author_sort | Rozenel, Sergio S. |
collection | PubMed |
description | In the title compound, C(14)H(12)N(2), the N⋯N distance is 2.719 (1) Å. The N—C—C—N torsion angle [0.9 (1)°] is close to the ideal value of 0° as expected. Bond lengths and angles are consistent with those observed for [1,10]phenanthroline and coordinated 5,6 dimethyl[1,10]phenanthroline. In the crystal, C—H⋯N hydrogen bonds link the molecules into C(4) chains running parallel to the b axis. Weak π–π interactions between benzene and pyridine rings [centroid–centroid distance = 3.5337 (7) Å] and between benzene rings [centroid–centroid distances = 3.6627 (7) and 3.8391 (7)Å] also occur. |
format | Online Article Text |
id | pubmed-3790421 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37904212013-10-04 5,6-Dimethyl-1,10-phenanthroline Rozenel, Sergio S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)N(2), the N⋯N distance is 2.719 (1) Å. The N—C—C—N torsion angle [0.9 (1)°] is close to the ideal value of 0° as expected. Bond lengths and angles are consistent with those observed for [1,10]phenanthroline and coordinated 5,6 dimethyl[1,10]phenanthroline. In the crystal, C—H⋯N hydrogen bonds link the molecules into C(4) chains running parallel to the b axis. Weak π–π interactions between benzene and pyridine rings [centroid–centroid distance = 3.5337 (7) Å] and between benzene rings [centroid–centroid distances = 3.6627 (7) and 3.8391 (7)Å] also occur. International Union of Crystallography 2013-09-18 /pmc/articles/PMC3790421/ /pubmed/24098240 http://dx.doi.org/10.1107/S1600536813025087 Text en © Sergio S. Rozenel 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rozenel, Sergio S. 5,6-Dimethyl-1,10-phenanthroline |
title | 5,6-Dimethyl-1,10-phenanthroline |
title_full | 5,6-Dimethyl-1,10-phenanthroline |
title_fullStr | 5,6-Dimethyl-1,10-phenanthroline |
title_full_unstemmed | 5,6-Dimethyl-1,10-phenanthroline |
title_short | 5,6-Dimethyl-1,10-phenanthroline |
title_sort | 5,6-dimethyl-1,10-phenanthroline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790421/ https://www.ncbi.nlm.nih.gov/pubmed/24098240 http://dx.doi.org/10.1107/S1600536813025087 |
work_keys_str_mv | AT rozenelsergios 56dimethyl110phenanthroline |