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5,6-Dimeth­yl-1,10-phenanthroline

In the title compound, C(14)H(12)N(2), the N⋯N distance is 2.719 (1) Å. The N—C—C—N torsion angle [0.9 (1)°] is close to the ideal value of 0° as expected. Bond lengths and angles are consistent with those observed for [1,10]phenanthroline and coordinated 5,6 dimeth­yl[1,10]phenanthroline. In the cr...

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Autor principal: Rozenel, Sergio S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790421/
https://www.ncbi.nlm.nih.gov/pubmed/24098240
http://dx.doi.org/10.1107/S1600536813025087
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author Rozenel, Sergio S.
author_facet Rozenel, Sergio S.
author_sort Rozenel, Sergio S.
collection PubMed
description In the title compound, C(14)H(12)N(2), the N⋯N distance is 2.719 (1) Å. The N—C—C—N torsion angle [0.9 (1)°] is close to the ideal value of 0° as expected. Bond lengths and angles are consistent with those observed for [1,10]phenanthroline and coordinated 5,6 dimeth­yl[1,10]phenanthroline. In the crystal, C—H⋯N hydrogen bonds link the mol­ecules into C(4) chains running parallel to the b axis. Weak π–π inter­actions between benzene and pyridine rings [centroid–centroid distance = 3.5337 (7) Å] and between benzene rings [centroid–centroid distances = 3.6627 (7) and 3.8391 (7)Å] also occur.
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spelling pubmed-37904212013-10-04 5,6-Dimeth­yl-1,10-phenanthroline Rozenel, Sergio S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)N(2), the N⋯N distance is 2.719 (1) Å. The N—C—C—N torsion angle [0.9 (1)°] is close to the ideal value of 0° as expected. Bond lengths and angles are consistent with those observed for [1,10]phenanthroline and coordinated 5,6 dimeth­yl[1,10]phenanthroline. In the crystal, C—H⋯N hydrogen bonds link the mol­ecules into C(4) chains running parallel to the b axis. Weak π–π inter­actions between benzene and pyridine rings [centroid–centroid distance = 3.5337 (7) Å] and between benzene rings [centroid–centroid distances = 3.6627 (7) and 3.8391 (7)Å] also occur. International Union of Crystallography 2013-09-18 /pmc/articles/PMC3790421/ /pubmed/24098240 http://dx.doi.org/10.1107/S1600536813025087 Text en © Sergio S. Rozenel 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rozenel, Sergio S.
5,6-Dimeth­yl-1,10-phenanthroline
title 5,6-Dimeth­yl-1,10-phenanthroline
title_full 5,6-Dimeth­yl-1,10-phenanthroline
title_fullStr 5,6-Dimeth­yl-1,10-phenanthroline
title_full_unstemmed 5,6-Dimeth­yl-1,10-phenanthroline
title_short 5,6-Dimeth­yl-1,10-phenanthroline
title_sort 5,6-dimeth­yl-1,10-phenanthroline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790421/
https://www.ncbi.nlm.nih.gov/pubmed/24098240
http://dx.doi.org/10.1107/S1600536813025087
work_keys_str_mv AT rozenelsergios 56dimethyl110phenanthroline