Methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate

In the title compound, C(32)H(25)NO(5), the furan and pyrrole rings each adopt an envelope conformation, the respective flap atoms being the C atom bearing the pyrene substituent and the CH(2) atom adjacent to the N atom. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen...

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Detalles Bibliográficos
Autores principales: Sharmila, P., Jagadeesan, G., Raju, Rajesh, Raghavachary, Raghunathan, Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790429/
https://www.ncbi.nlm.nih.gov/pubmed/24098248
http://dx.doi.org/10.1107/S1600536813024951
Descripción
Sumario:In the title compound, C(32)H(25)NO(5), the furan and pyrrole rings each adopt an envelope conformation, the respective flap atoms being the C atom bearing the pyrene substituent and the CH(2) atom adjacent to the N atom. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond. In the crystal, C—H⋯O contacts link the mol­ecules, forming a two-dimensional network parallel to (001).

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