Methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate

In the title compound, C(32)H(25)NO(5), the furan and pyrrole rings each adopt an envelope conformation, the respective flap atoms being the C atom bearing the pyrene substituent and the CH(2) atom adjacent to the N atom. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen...

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Autores principales: Sharmila, P., Jagadeesan, G., Raju, Rajesh, Raghavachary, Raghunathan, Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790429/
https://www.ncbi.nlm.nih.gov/pubmed/24098248
http://dx.doi.org/10.1107/S1600536813024951
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author Sharmila, P.
Jagadeesan, G.
Raju, Rajesh
Raghavachary, Raghunathan
Aravindhan, S.
author_facet Sharmila, P.
Jagadeesan, G.
Raju, Rajesh
Raghavachary, Raghunathan
Aravindhan, S.
author_sort Sharmila, P.
collection PubMed
description In the title compound, C(32)H(25)NO(5), the furan and pyrrole rings each adopt an envelope conformation, the respective flap atoms being the C atom bearing the pyrene substituent and the CH(2) atom adjacent to the N atom. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond. In the crystal, C—H⋯O contacts link the mol­ecules, forming a two-dimensional network parallel to (001).
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spelling pubmed-37904292013-10-04 Methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate Sharmila, P. Jagadeesan, G. Raju, Rajesh Raghavachary, Raghunathan Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(25)NO(5), the furan and pyrrole rings each adopt an envelope conformation, the respective flap atoms being the C atom bearing the pyrene substituent and the CH(2) atom adjacent to the N atom. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond. In the crystal, C—H⋯O contacts link the mol­ecules, forming a two-dimensional network parallel to (001). International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790429/ /pubmed/24098248 http://dx.doi.org/10.1107/S1600536813024951 Text en © Sharmila et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sharmila, P.
Jagadeesan, G.
Raju, Rajesh
Raghavachary, Raghunathan
Aravindhan, S.
Methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate
title Methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate
title_full Methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate
title_fullStr Methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate
title_full_unstemmed Methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate
title_short Methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate
title_sort methyl 9-hy­droxy-15-methyl-2-oxo-11-(pyren-1-yl)-10-oxa-15-aza­tetra­cyclo­[7.6.0.0(1,12).0(3,8)]penta­deca-3(8),4,6-triene-12-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790429/
https://www.ncbi.nlm.nih.gov/pubmed/24098248
http://dx.doi.org/10.1107/S1600536813024951
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