N-(4-Bromo­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine

In the title compound, C(12)H(16)BrNO(2), the dioxane ring adopts a chair conformation and its mean plane makes a dihedral angle of 60.63 (12)° with the 4-bromo­phenyl ring. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring mot...

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Autores principales: Fatima, Zeenat, Rambabu, Gottimukkala, Reddy, Bandapalli Palakshi, Vijayakumar, Vijayaparthasarathi, Velmurugan, Devadasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790436/
https://www.ncbi.nlm.nih.gov/pubmed/24098255
http://dx.doi.org/10.1107/S1600536813025750
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author Fatima, Zeenat
Rambabu, Gottimukkala
Reddy, Bandapalli Palakshi
Vijayakumar, Vijayaparthasarathi
Velmurugan, Devadasan
author_facet Fatima, Zeenat
Rambabu, Gottimukkala
Reddy, Bandapalli Palakshi
Vijayakumar, Vijayaparthasarathi
Velmurugan, Devadasan
author_sort Fatima, Zeenat
collection PubMed
description In the title compound, C(12)H(16)BrNO(2), the dioxane ring adopts a chair conformation and its mean plane makes a dihedral angle of 60.63 (12)° with the 4-bromo­phenyl ring. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. These dimers are consolidated by pairs of C—H⋯O hydrogen bonds with an R (2) (2)(16) ring motif. Adjacent dimers are connected via C—H⋯O hydrogen bonds, forming infinite chains propagating along the c-axis direction.
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spelling pubmed-37904362013-10-04 N-(4-Bromo­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine Fatima, Zeenat Rambabu, Gottimukkala Reddy, Bandapalli Palakshi Vijayakumar, Vijayaparthasarathi Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(16)BrNO(2), the dioxane ring adopts a chair conformation and its mean plane makes a dihedral angle of 60.63 (12)° with the 4-bromo­phenyl ring. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. These dimers are consolidated by pairs of C—H⋯O hydrogen bonds with an R (2) (2)(16) ring motif. Adjacent dimers are connected via C—H⋯O hydrogen bonds, forming infinite chains propagating along the c-axis direction. International Union of Crystallography 2013-09-21 /pmc/articles/PMC3790436/ /pubmed/24098255 http://dx.doi.org/10.1107/S1600536813025750 Text en © Fatima et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fatima, Zeenat
Rambabu, Gottimukkala
Reddy, Bandapalli Palakshi
Vijayakumar, Vijayaparthasarathi
Velmurugan, Devadasan
N-(4-Bromo­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title N-(4-Bromo­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_full N-(4-Bromo­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_fullStr N-(4-Bromo­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_full_unstemmed N-(4-Bromo­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_short N-(4-Bromo­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
title_sort n-(4-bromo­phen­yl)-2,6-dimethyl-1,3-dioxan-4-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790436/
https://www.ncbi.nlm.nih.gov/pubmed/24098255
http://dx.doi.org/10.1107/S1600536813025750
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