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2,2′-{[(1E,1′E)-(Cyclo­hexane-1,4-diyl)­bis(aza­nylyl­idene)]bis­(ethan-1-yl-1-yl­idene)}diphenol

The title compound, C(22)H(26)N(2)O(2), crystallizes with three independent mol­ecules, two of which are situated on inversion centers, so the asymmetric unit contains two independent half-mol­ecules and one mol­ecule in a general position. The two hy­droxy groups in each mol­ecule are involved in i...

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Detalles Bibliográficos
Autores principales: Lakshmi, S. H. Anjana, Kandaswamy, M., Ramkumar, V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790448/
https://www.ncbi.nlm.nih.gov/pubmed/24098267
http://dx.doi.org/10.1107/S1600536813026123
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author Lakshmi, S. H. Anjana
Kandaswamy, M.
Ramkumar, V.
author_facet Lakshmi, S. H. Anjana
Kandaswamy, M.
Ramkumar, V.
author_sort Lakshmi, S. H. Anjana
collection PubMed
description The title compound, C(22)H(26)N(2)O(2), crystallizes with three independent mol­ecules, two of which are situated on inversion centers, so the asymmetric unit contains two independent half-mol­ecules and one mol­ecule in a general position. The two hy­droxy groups in each mol­ecule are involved in intra­molecular O—H⋯N hydrogen bonds, which generate S(6) rings. In the crystal, weak inter­molecular C—H⋯π inter­actions link the mol­ecules into two crystallographically independent columns propagating along [001]; one column consists of mol­ecules in general positions, while the other column is built from alternating independent centrosymmetric mol­ecules.
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spelling pubmed-37904482013-10-04 2,2′-{[(1E,1′E)-(Cyclo­hexane-1,4-diyl)­bis(aza­nylyl­idene)]bis­(ethan-1-yl-1-yl­idene)}diphenol Lakshmi, S. H. Anjana Kandaswamy, M. Ramkumar, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(26)N(2)O(2), crystallizes with three independent mol­ecules, two of which are situated on inversion centers, so the asymmetric unit contains two independent half-mol­ecules and one mol­ecule in a general position. The two hy­droxy groups in each mol­ecule are involved in intra­molecular O—H⋯N hydrogen bonds, which generate S(6) rings. In the crystal, weak inter­molecular C—H⋯π inter­actions link the mol­ecules into two crystallographically independent columns propagating along [001]; one column consists of mol­ecules in general positions, while the other column is built from alternating independent centrosymmetric mol­ecules. International Union of Crystallography 2013-09-28 /pmc/articles/PMC3790448/ /pubmed/24098267 http://dx.doi.org/10.1107/S1600536813026123 Text en © Lakshmi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lakshmi, S. H. Anjana
Kandaswamy, M.
Ramkumar, V.
2,2′-{[(1E,1′E)-(Cyclo­hexane-1,4-diyl)­bis(aza­nylyl­idene)]bis­(ethan-1-yl-1-yl­idene)}diphenol
title 2,2′-{[(1E,1′E)-(Cyclo­hexane-1,4-diyl)­bis(aza­nylyl­idene)]bis­(ethan-1-yl-1-yl­idene)}diphenol
title_full 2,2′-{[(1E,1′E)-(Cyclo­hexane-1,4-diyl)­bis(aza­nylyl­idene)]bis­(ethan-1-yl-1-yl­idene)}diphenol
title_fullStr 2,2′-{[(1E,1′E)-(Cyclo­hexane-1,4-diyl)­bis(aza­nylyl­idene)]bis­(ethan-1-yl-1-yl­idene)}diphenol
title_full_unstemmed 2,2′-{[(1E,1′E)-(Cyclo­hexane-1,4-diyl)­bis(aza­nylyl­idene)]bis­(ethan-1-yl-1-yl­idene)}diphenol
title_short 2,2′-{[(1E,1′E)-(Cyclo­hexane-1,4-diyl)­bis(aza­nylyl­idene)]bis­(ethan-1-yl-1-yl­idene)}diphenol
title_sort 2,2′-{[(1e,1′e)-(cyclo­hexane-1,4-diyl)­bis(aza­nylyl­idene)]bis­(ethan-1-yl-1-yl­idene)}diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790448/
https://www.ncbi.nlm.nih.gov/pubmed/24098267
http://dx.doi.org/10.1107/S1600536813026123
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