Cargando…
2,2′-{[(1E,1′E)-(Cyclohexane-1,4-diyl)bis(azanylylidene)]bis(ethan-1-yl-1-ylidene)}diphenol
The title compound, C(22)H(26)N(2)O(2), crystallizes with three independent molecules, two of which are situated on inversion centers, so the asymmetric unit contains two independent half-molecules and one molecule in a general position. The two hydroxy groups in each molecule are involved in i...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790448/ https://www.ncbi.nlm.nih.gov/pubmed/24098267 http://dx.doi.org/10.1107/S1600536813026123 |
_version_ | 1782286599913996288 |
---|---|
author | Lakshmi, S. H. Anjana Kandaswamy, M. Ramkumar, V. |
author_facet | Lakshmi, S. H. Anjana Kandaswamy, M. Ramkumar, V. |
author_sort | Lakshmi, S. H. Anjana |
collection | PubMed |
description | The title compound, C(22)H(26)N(2)O(2), crystallizes with three independent molecules, two of which are situated on inversion centers, so the asymmetric unit contains two independent half-molecules and one molecule in a general position. The two hydroxy groups in each molecule are involved in intramolecular O—H⋯N hydrogen bonds, which generate S(6) rings. In the crystal, weak intermolecular C—H⋯π interactions link the molecules into two crystallographically independent columns propagating along [001]; one column consists of molecules in general positions, while the other column is built from alternating independent centrosymmetric molecules. |
format | Online Article Text |
id | pubmed-3790448 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37904482013-10-04 2,2′-{[(1E,1′E)-(Cyclohexane-1,4-diyl)bis(azanylylidene)]bis(ethan-1-yl-1-ylidene)}diphenol Lakshmi, S. H. Anjana Kandaswamy, M. Ramkumar, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(26)N(2)O(2), crystallizes with three independent molecules, two of which are situated on inversion centers, so the asymmetric unit contains two independent half-molecules and one molecule in a general position. The two hydroxy groups in each molecule are involved in intramolecular O—H⋯N hydrogen bonds, which generate S(6) rings. In the crystal, weak intermolecular C—H⋯π interactions link the molecules into two crystallographically independent columns propagating along [001]; one column consists of molecules in general positions, while the other column is built from alternating independent centrosymmetric molecules. International Union of Crystallography 2013-09-28 /pmc/articles/PMC3790448/ /pubmed/24098267 http://dx.doi.org/10.1107/S1600536813026123 Text en © Lakshmi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Lakshmi, S. H. Anjana Kandaswamy, M. Ramkumar, V. 2,2′-{[(1E,1′E)-(Cyclohexane-1,4-diyl)bis(azanylylidene)]bis(ethan-1-yl-1-ylidene)}diphenol |
title | 2,2′-{[(1E,1′E)-(Cyclohexane-1,4-diyl)bis(azanylylidene)]bis(ethan-1-yl-1-ylidene)}diphenol |
title_full | 2,2′-{[(1E,1′E)-(Cyclohexane-1,4-diyl)bis(azanylylidene)]bis(ethan-1-yl-1-ylidene)}diphenol |
title_fullStr | 2,2′-{[(1E,1′E)-(Cyclohexane-1,4-diyl)bis(azanylylidene)]bis(ethan-1-yl-1-ylidene)}diphenol |
title_full_unstemmed | 2,2′-{[(1E,1′E)-(Cyclohexane-1,4-diyl)bis(azanylylidene)]bis(ethan-1-yl-1-ylidene)}diphenol |
title_short | 2,2′-{[(1E,1′E)-(Cyclohexane-1,4-diyl)bis(azanylylidene)]bis(ethan-1-yl-1-ylidene)}diphenol |
title_sort | 2,2′-{[(1e,1′e)-(cyclohexane-1,4-diyl)bis(azanylylidene)]bis(ethan-1-yl-1-ylidene)}diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790448/ https://www.ncbi.nlm.nih.gov/pubmed/24098267 http://dx.doi.org/10.1107/S1600536813026123 |
work_keys_str_mv | AT lakshmishanjana 221e1ecyclohexane14diylbisazanylylidenebisethan1yl1ylidenediphenol AT kandaswamym 221e1ecyclohexane14diylbisazanylylidenebisethan1yl1ylidenediphenol AT ramkumarv 221e1ecyclohexane14diylbisazanylylidenebisethan1yl1ylidenediphenol |