4′-Acetyl-3′′-carbamoyl-[1,1′:3′,1′′-terphen­yl]-2-carb­oxy­lic acid

In the title m-terphenyl derivative, C(22)H(17)NO(4), the dihedral angles between the aromatic rings of the benzoic acid–acetophenone, acetophenone–benzamide and benzoic acid–benzamide units are 45.39 (8), 48.02 (8) and 42.93 (8)°, respectively. The carbamoyl and carboxyl groups are disordered with...

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Detalles Bibliográficos
Autores principales: Ishikawa, Yoshinobu, Yoshida, Nanako, Suzuki, Takafumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790450/
https://www.ncbi.nlm.nih.gov/pubmed/24098269
http://dx.doi.org/10.1107/S1600536813026482
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author Ishikawa, Yoshinobu
Yoshida, Nanako
Suzuki, Takafumi
author_facet Ishikawa, Yoshinobu
Yoshida, Nanako
Suzuki, Takafumi
author_sort Ishikawa, Yoshinobu
collection PubMed
description In the title m-terphenyl derivative, C(22)H(17)NO(4), the dihedral angles between the aromatic rings of the benzoic acid–acetophenone, acetophenone–benzamide and benzoic acid–benzamide units are 45.39 (8), 48.02 (8) and 42.93 (8)°, respectively. The carbamoyl and carboxyl groups are disordered with a refined occupancy ratio of 0.558 (15):0.442 (15). In the crystal, mol­ecules are linked through O—H⋯O and N—H⋯O hydrogen bonds between terminal carboxyl and carbamoyl groups in a bidentate manner, and anti­parallel helices are formed which extend along the b-axis direction.
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spelling pubmed-37904502013-10-04 4′-Acetyl-3′′-carbamoyl-[1,1′:3′,1′′-terphen­yl]-2-carb­oxy­lic acid Ishikawa, Yoshinobu Yoshida, Nanako Suzuki, Takafumi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title m-terphenyl derivative, C(22)H(17)NO(4), the dihedral angles between the aromatic rings of the benzoic acid–acetophenone, acetophenone–benzamide and benzoic acid–benzamide units are 45.39 (8), 48.02 (8) and 42.93 (8)°, respectively. The carbamoyl and carboxyl groups are disordered with a refined occupancy ratio of 0.558 (15):0.442 (15). In the crystal, mol­ecules are linked through O—H⋯O and N—H⋯O hydrogen bonds between terminal carboxyl and carbamoyl groups in a bidentate manner, and anti­parallel helices are formed which extend along the b-axis direction. International Union of Crystallography 2013-09-28 /pmc/articles/PMC3790450/ /pubmed/24098269 http://dx.doi.org/10.1107/S1600536813026482 Text en © Ishikawa et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ishikawa, Yoshinobu
Yoshida, Nanako
Suzuki, Takafumi
4′-Acetyl-3′′-carbamoyl-[1,1′:3′,1′′-terphen­yl]-2-carb­oxy­lic acid
title 4′-Acetyl-3′′-carbamoyl-[1,1′:3′,1′′-terphen­yl]-2-carb­oxy­lic acid
title_full 4′-Acetyl-3′′-carbamoyl-[1,1′:3′,1′′-terphen­yl]-2-carb­oxy­lic acid
title_fullStr 4′-Acetyl-3′′-carbamoyl-[1,1′:3′,1′′-terphen­yl]-2-carb­oxy­lic acid
title_full_unstemmed 4′-Acetyl-3′′-carbamoyl-[1,1′:3′,1′′-terphen­yl]-2-carb­oxy­lic acid
title_short 4′-Acetyl-3′′-carbamoyl-[1,1′:3′,1′′-terphen­yl]-2-carb­oxy­lic acid
title_sort 4′-acetyl-3′′-carbamoyl-[1,1′:3′,1′′-terphen­yl]-2-carb­oxy­lic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790450/
https://www.ncbi.nlm.nih.gov/pubmed/24098269
http://dx.doi.org/10.1107/S1600536813026482
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