Tetraammine(carbonato-κ(2) O,O′)cobalt(III) perchlorate

In the title complex, [Co(CO(3))(NH(3))(4)]ClO(4), both the cation and anion lie on a mirror plane. The Co(III) ion is coordinated by two NH(3) ligands and a chelating carbonato ligand in the equatorial sites and by two NH(3) groups in the axial sites, forming a distorted octa­hedral geometry. In th...

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Autores principales: Mohan, Singaravelu Chandra, Jenniefer, Samson Jegan, Muthiah, Packianathan Thomas, Jothivenkatachalam, Kandasamy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793665/
https://www.ncbi.nlm.nih.gov/pubmed/24109252
http://dx.doi.org/10.1107/S1600536813018187
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author Mohan, Singaravelu Chandra
Jenniefer, Samson Jegan
Muthiah, Packianathan Thomas
Jothivenkatachalam, Kandasamy
author_facet Mohan, Singaravelu Chandra
Jenniefer, Samson Jegan
Muthiah, Packianathan Thomas
Jothivenkatachalam, Kandasamy
author_sort Mohan, Singaravelu Chandra
collection PubMed
description In the title complex, [Co(CO(3))(NH(3))(4)]ClO(4), both the cation and anion lie on a mirror plane. The Co(III) ion is coordinated by two NH(3) ligands and a chelating carbonato ligand in the equatorial sites and by two NH(3) groups in the axial sites, forming a distorted octa­hedral geometry. In the crystal, N—H⋯O hydrogen bonds connect the anions and cations, forming a three-dimensional network.
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spelling pubmed-37936652013-10-09 Tetraammine(carbonato-κ(2) O,O′)cobalt(III) perchlorate Mohan, Singaravelu Chandra Jenniefer, Samson Jegan Muthiah, Packianathan Thomas Jothivenkatachalam, Kandasamy Acta Crystallogr Sect E Struct Rep Online Inorganic Papers In the title complex, [Co(CO(3))(NH(3))(4)]ClO(4), both the cation and anion lie on a mirror plane. The Co(III) ion is coordinated by two NH(3) ligands and a chelating carbonato ligand in the equatorial sites and by two NH(3) groups in the axial sites, forming a distorted octa­hedral geometry. In the crystal, N—H⋯O hydrogen bonds connect the anions and cations, forming a three-dimensional network. International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793665/ /pubmed/24109252 http://dx.doi.org/10.1107/S1600536813018187 Text en © Mohan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Mohan, Singaravelu Chandra
Jenniefer, Samson Jegan
Muthiah, Packianathan Thomas
Jothivenkatachalam, Kandasamy
Tetraammine(carbonato-κ(2) O,O′)cobalt(III) perchlorate
title Tetraammine(carbonato-κ(2) O,O′)cobalt(III) perchlorate
title_full Tetraammine(carbonato-κ(2) O,O′)cobalt(III) perchlorate
title_fullStr Tetraammine(carbonato-κ(2) O,O′)cobalt(III) perchlorate
title_full_unstemmed Tetraammine(carbonato-κ(2) O,O′)cobalt(III) perchlorate
title_short Tetraammine(carbonato-κ(2) O,O′)cobalt(III) perchlorate
title_sort tetraammine(carbonato-κ(2) o,o′)cobalt(iii) perchlorate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793665/
https://www.ncbi.nlm.nih.gov/pubmed/24109252
http://dx.doi.org/10.1107/S1600536813018187
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