RbCuFe(PO(4))(2)

A new iron phosphate, rubidium copper(II) iron(III) bis­(phosphate), RbCuFe(PO(4))(2), has been synthesized as single crystals by the flux method. This compound is isostructural with KCuFe(PO(4))(2) [Badri et al. (2011 ▶), J. Solid State Chem. 184, 937–944]. Its structure is built up from Cu(2)O(8)...

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Detalles Bibliográficos
Autores principales: Badri, Abdessalem, Hidouri, Mourad, Ben Amara, Mongi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793670/
https://www.ncbi.nlm.nih.gov/pubmed/24109257
http://dx.doi.org/10.1107/S1600536813019569
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author Badri, Abdessalem
Hidouri, Mourad
Ben Amara, Mongi
author_facet Badri, Abdessalem
Hidouri, Mourad
Ben Amara, Mongi
author_sort Badri, Abdessalem
collection PubMed
description A new iron phosphate, rubidium copper(II) iron(III) bis­(phosphate), RbCuFe(PO(4))(2), has been synthesized as single crystals by the flux method. This compound is isostructural with KCuFe(PO(4))(2) [Badri et al. (2011 ▶), J. Solid State Chem. 184, 937–944]. Its structure is built up from Cu(2)O(8) units of edge-sharing CuO(5) polyhedra, inter­connected by FeO(6) octa­hedra through common corners to form undulating chains that extend infinitely along the [011] and [01-1] directions. The linkage of such chains is ensured by the PO(4) tetra­edra and the resulting three-dimensional framework forms quasi-elliptic tunnels parallel to the [101] direction in which the Rb(+) cations are located.
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spelling pubmed-37936702013-10-09 RbCuFe(PO(4))(2) Badri, Abdessalem Hidouri, Mourad Ben Amara, Mongi Acta Crystallogr Sect E Struct Rep Online Inorganic Papers A new iron phosphate, rubidium copper(II) iron(III) bis­(phosphate), RbCuFe(PO(4))(2), has been synthesized as single crystals by the flux method. This compound is isostructural with KCuFe(PO(4))(2) [Badri et al. (2011 ▶), J. Solid State Chem. 184, 937–944]. Its structure is built up from Cu(2)O(8) units of edge-sharing CuO(5) polyhedra, inter­connected by FeO(6) octa­hedra through common corners to form undulating chains that extend infinitely along the [011] and [01-1] directions. The linkage of such chains is ensured by the PO(4) tetra­edra and the resulting three-dimensional framework forms quasi-elliptic tunnels parallel to the [101] direction in which the Rb(+) cations are located. International Union of Crystallography 2013-07-24 /pmc/articles/PMC3793670/ /pubmed/24109257 http://dx.doi.org/10.1107/S1600536813019569 Text en © Badri et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Badri, Abdessalem
Hidouri, Mourad
Ben Amara, Mongi
RbCuFe(PO(4))(2)
title RbCuFe(PO(4))(2)
title_full RbCuFe(PO(4))(2)
title_fullStr RbCuFe(PO(4))(2)
title_full_unstemmed RbCuFe(PO(4))(2)
title_short RbCuFe(PO(4))(2)
title_sort rbcufe(po(4))(2)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793670/
https://www.ncbi.nlm.nih.gov/pubmed/24109257
http://dx.doi.org/10.1107/S1600536813019569
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AT hidourimourad rbcufepo42
AT benamaramongi rbcufepo42

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