Poly[μ-aqua-μ-(N,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium]

In the title compound, [K(C(7)H(6)Cl(2)NO(2)S)(H(2)O)](n), the K(+) cation is hepta­coordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methyl­benzene­sulfonamidate anions and a Cl atom of one of the anions. Further, K—O—K bridges form extensive polymeric c...

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Detalles Bibliográficos
Autores principales: Spandana, H. S., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793672/
https://www.ncbi.nlm.nih.gov/pubmed/24109259
http://dx.doi.org/10.1107/S1600536813015845
Descripción
Sumario:In the title compound, [K(C(7)H(6)Cl(2)NO(2)S)(H(2)O)](n), the K(+) cation is hepta­coordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methyl­benzene­sulfonamidate anions and a Cl atom of one of the anions. Further, K—O—K bridges form extensive polymeric chains along the b axis. In the crystal structure, the anions are linked into layers parallel to (100) by O—H⋯Cl and O—H⋯N hydrogen bonds.

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